以NiSO4、ZnSO4和Nd(NO3)3为原料,采用共沉淀快速冷冻法制备出了复合掺杂稀土Nd(III)和Zn(II)的非晶态氢氧化镍粉体材料。测试发现:样品材料微结构无序性强,结晶水含量较高。将样品材料制备成镍电极并组装成MH—Ni电池,在80mA/g恒电流充电5.5h、40mA/g恒电流放电、终止电压为1.0V的充放电制度下,复合掺杂6%Nd(III)和6%Zn(II)样品材料电池的放电平台为1.2624V,放电比容量为343.12mAh/g,远高于目前应用的B-Ni(OH)2电极活性材料的放电比容量。
Amorphous nickel hydroxide eodoped in rare earth Nd (III) and Zn (II) can be synthesized by the method of quick cryoprecipition with NiSO4, ZnSO4 and Nd ( NO3 ) 3. The characterization shows that the microstructure of sample contains some crystal water,and the disordering degree is strong. A simulated MH-Ni battery composed of amorphous nickel hydroxide particles as activity material is assembled. When the sample codoped in 6% Nd(III) and 6%Zn(II) is charged at 80 mA/g for 5.5 h and discharged at 40 mA/g to a cut-off potential of 1.0 V, the discharge voltage plateau is smooth at 1. 262 4 V, the discharge specific capacity can reach as 343.12 mAh/g, higher than discharge specific capacity of β-Ni(OH) 2 electrode activity material.