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中文摘要：
以Cr2O7^2-／Cr^3＋作为间接氧化剂电氧化环己醇制备己二酸．应用正交实验优化工艺条件，得出在原料比n（环己醇）：n（Cr2O7^2-）=0．4：1，t=35℃和CH2SO4=5mol·L^-1条件下己二酸的收率可达70．29％．同时研究了Ag2SO4、（NH4）：SO4、H2SO4浓度、电流密度对Cr^3＋电氧化为Cr2O7^2-的影响，Cr^3＋的转化率可达82．52％．
英文摘要：
Adipic acid was synthesized by electro-oxidation of cyclohexanol taking Cr2O7^2-/Cr^3＋ as indirect oxidant. The best technological conditions were optimized by orthogonal experiment . The optimum condition are as follows ： the temperature is 35 ℃, ratio of crude material is n （cyclohexanol） ： n （ Cr2O7^2- ） = 0.4：1 and concentration of H2SO4 is 4 mol·L^-1. Under these conditions, the yield of adipic acid can reach 70.29%. Moreover, The effects of concentration of Ag2SO4, （NH4） 2SO4, H2SO4and current density on the formation of Cr2O7^2- were also explored . The rate of Cr^3＋ conversion can reach 82.52%.
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