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Wet-chemistry synthesis of cobalt carbide nanoparticles as highly active and stable electrocatalyst for hydrogen evolution reaction
  • ISSN号:1000-6818
  • 期刊名称:《物理化学学报》
  • 时间:0
  • 分类:O[理学]
  • 作者机构:[1]College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China, [2]State Key Laboratory of Separation Membranes and Membrane Processes, Department of Chemical Engineering, Tianjin Polytechnic University, Tianjin 300387, China, [3]Israel Chemicals Limited, Shanghai 200021, China
  • 相关基金:Acknowledgements This work was financially supported by the National Natural Science Foundation of China (Nos. 21473003 and 21303119) and the National Basic Research Program of China (No. 2013CB933100). C. Y. acknowledges the financial support of China Postdoctoral Science Foundation (No. 2015M580011). XAS analysis was performed at the Beijing Synchrotron Radiation Fadlity.
中文摘要:

转变金属碳化物(TMC ) nanomaterials 正在答应选择到磅,并且广泛地为电气化学的氢进化反应被用作异构的 electrocatalysts (她的) 。在这个工作,综合的导致溴化物的湿化学的策略公司 2 C nanoparticles (NP ) 被开发。如此的 NP 展出了高 electrocatalytic 活动(= 为 j = 的 181 mV 10 妈

英文摘要:

Transition metal carbide (TMC) nanomaterials are promising alternatives to Pt, and are widely used as heterogeneous electrocatalysts for the electrochemical hydrogen evolution reaction (HER). In this work, a bromide-induced wet-chemistry strategy to synthesize Co2C nanoparticles (NPs) was developed. Such NPs exhibited high electrocatalytic activity (η= 181 mV for j = -10 mA·cm^-2) and long-term stability (no obvious performance decrease after 4,000 cycles) for the HER. This study will pave the way for the design and fabrication of TMC NPs via a wet- chemistry method, and will have significant impacts on broader areas such as nanocatalysis and energy conversion.

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期刊信息
  • 《物理化学学报》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:北京大学化学与分子工程学院承办
  • 主编:刘忠范
  • 地址:北京大学化学楼
  • 邮编:100871
  • 邮箱:whxb@pku.edu.cn
  • 电话:010-62751724
  • 国际标准刊号:ISSN:1000-6818
  • 国内统一刊号:ISSN:11-1892/O6
  • 邮发代号:82-163
  • 获奖情况:
  • 中文核心期刊
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  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国科学引文索引(扩展库),英国科学文摘数据库,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:24781