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Stereoselective Synthesis of 1-Aminocyclopropanecarboxylic Acid Derivatives via Ylide Cyclopropanation of Dehydroamino Acid Derivatives
  • ISSN号：1001-604X
  • 期刊名称：《中国化学：英文版》
  • 时间：0
  • 分类：O624.11[理学—有机化学;理学—化学] TQ453.4[化学工程—农药化工]
  • 作者机构：[1]Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Ma- terials Science, Soochow University, Suzhou, Jiangsu 215123, China, [2]State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, 345 Lingling Lu, Shanghai 200032, China
  • 相关基金：Project supported by the National Natural Science Foundation of China （Nos. 20821002, 20932008）, the Major State Basic Research Development Program （No. 2009CB825300）, and the Science and Technology Commission of Shanghai Municipality （No. Y0D00512E0）.
作者： 周锐[1], 邓贤明[2], 郑君成[2], 沈琪[1], 孙秀丽[2], 唐勇[1,2]
关键词： 环丙烷衍生物, 立体选择性合成, 硫叶立德, amino acids, enantioselectivity, annulation, ylides, stereoselective synthesis
中文摘要：

1-Aminocyclopropanecarboxylic 酸衍生物经由硫 ylide 从容易地可得到的 dehydroamino 酸衍生物被综合。不同 ylides 的一个范围被采用，相应 aminocyclopropanes 在好收益与合理 diastereoselection 被负担得起。

英文摘要：

1-Aminocyclopropanecarboxylic acid derivatives are synthesized from readily available dehydroamino acid de- rivatives via sulfur ylide. A range of different ylides are employed and the corresponding aminocyclopropanes are afforded with reasonable diastereoselection in good yields.

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期刊信息
  • 《中国化学：英文版》
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  • 主办单位:中国化学会
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  • 地址：上海市枫林路354号中科院上海有机化学研究所
  • 邮编：200032
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  • 电话：021-54925243
  • 国际标准刊号：ISSN：1001-604X
  • 国内统一刊号：ISSN：31-1547/O6
  • 邮发代号:4-646
  • 获奖情况:
  • 中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 美国化学文摘（网络版）,荷兰文摘与引文数据库,美国科学引文索引（扩展库）,日本日本科学技术振兴机构数据库,英国英国皇家化学学会文摘
  • 被引量:175