利用油页岩为原料,首先采用碱溶-沉淀法制备了白炭黑,降低了油页岩中的SiO2的含量,具体工艺条件为:NaOH/SiO2(物质的量)=4,水/油页岩(质量)=1,100℃,6h,粒径≥0.15mm。然后采用酸浸法,制备了γ-Al2O3,降低了油页岩中的Al2O3和Fe2O3的含量,具体条件为:酸浸液中用NaOH溶液调整到pH=12.0,过滤分离,再用HCl调整溶液pH=6.0,使Al2O3和Fe2O3完全分离。最后得到了含量为71.6%的干酪根,并经FT-IR验证。
Silica was prepared by alkali dissolution-precipitation with oil shale as starting material, and the content of SiO2 in oil shale was reduced. The detailed processing conditions were as follows: molar ratio of NaOH to SiO2 was 4, mass ratio of water to oil shale was 1, the treating condition was at 100℃ for 6 h, and grain size was more than 0.15 mm. Then acid leaching of oil shale was performed to prepare 7-Al2O3, and the content of Al2O3 and Fe2O3 in oil shale was reduced too. The acid leachate solution was modulated to pH=12.0 by adding alkali solution, and a mixture of 7-Al2O3 and Fe2O3 was precipitated and filtered, then 7-Al2O3 and Fe2O3 were separated completely by adding acid solution to pH =6.0. Finally, the treated oil shale had a kerogen content of 71.60% and the kerogen was validated by FT-IR.