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YPO4:Tb荧光粉的制备及其VUV激发下的发光性能
  • ISSN号:1000-7032
  • 期刊名称:《发光学报》
  • 时间:0
  • 分类:O482.31[理学—固体物理;理学—物理]
  • 作者机构:[1]中国科学院激发态物理重点实验室,吉林长春130033, [2]中国科学院研究生院,北京100049
  • 相关基金:国家“863”计划(2002AA311160);国家自然科学基金(5017046,50102006)资助项目.
中文摘要:

采用共沉淀法制备了PDP用的绿色荧光粉YPO4:Tb。XRD、SEM等测试手段表明用此方法制备的YPO4:Tb相纯度高,所需的烧结温度低、颗粒分散性好、颗粒尺寸分布窄,且表面质量好。研究了YPO4:Tb在真空紫外光(VUV)激发下的发光性能,并对VUV激发下的发光机理进行初步探索。

英文摘要:

Lanthanide phosphates represent a class of materials with significant technological importance, and are extensively applied as laser, ceramic, sensor, and phosphor materials. Among various lanthanide phosphate compounds, the lanthanide doped lanthanide phosphates are extremely suitable for applications as phosphors owing to the transition between energy levels of lanthanide ions. The development and application of mercury-free lamps and plasma display panels (PDPs) induce considerable research interest in vacuum uhraviolet (VUV) excitation. Conventional solid-state reaction route requires high temperature calcinations, milling and grinding processes. The phosphor particles obtained by this method have an irregular shape, coarse surface, wide size distribution, and high aggregation. The solution co-precipitation technique was used to synthesize the green-emitting phosphor YPO4: Tb. Results indicate that the YPO4: Tb phosphor particles prepared by co-precipitation technique have almost spherical shape, smooth surface, narrow size distribution in 1 -2 p,m range, and low aggregation. The VUV excitation and emissions under 147 nm excitation are investigated. The VUV excitation spectrum of Tb doped YPO4 suggests that phosphors have a high absorption near 147 nm, which is ascribed to the host absorption. The luminous emission of YPO4: Tb precipitates calcinated in 800 - 1 000℃ increases with the increase of calcination temperature due to the improvement of crystallinity. The luminous efficiency of YPO4: Tb obtained from solution co-precipitation is higher than that obtained from conventional solid state route.

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期刊信息
  • 《发光学报》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国物理学会发光分会 中国科学院长春光学精密机械与物理研究所
  • 主编:申德振
  • 地址:长春市东南湖大路3888号
  • 邮编:130033
  • 邮箱:fgxbt@126.com
  • 电话:0431-86176862
  • 国际标准刊号:ISSN:1000-7032
  • 国内统一刊号:ISSN:22-1116/O4
  • 邮发代号:12-312
  • 获奖情况:
  • 物理学类核心期刊,2000年获中国科学院优秀期刊二等奖,中国期刊方阵“双效”期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:7320