中文摘要：

在纤维素LiCl/DMAc均相溶液中,通过氯乙酰氯（ClC2OCl）与纤维素的均相酰化反应制得纤维素氯乙酸酯（Cellulose-ClAc）后,将其溶解在DMAc中,在FeCl2/4-二甲氨基吡啶（DMAP）的催化作用下,引发甲基丙烯酸丁酯（BMA）的均相ATRP聚合反应,制备了纤维素/BMA接枝共聚物（Cellulose-g-PBMA）,考察了反应时间、反应温度、反应物配比等对酰化及接枝聚合反应的影响,并通过测试Cellulose-g-PBMA薄膜的接触角,对最终产物的疏水性能进行了研究;采用FTIR、NMR、SEM、TEM、AFM等分析手段对Cellulose-ClAc及Cellulose-g-PBMA的结构进行了表征;利用GPC分析了接枝聚合反应的活性特征。

英文摘要：

Cellulose graft poly（butyl methacrylate） copolymers （Cellulose-g-PBMA） were prepared by homogeneous atom transfer radical polymerization （ATRP） process. Cellulose chloroacetate （Cellulose-C1Ac）, as macroinitiator, was synthesized first by direct acylation of cotton pulp cellulose with chloroacetyl chloride （CIC2OCI） in cellulose/LiC1/DMAc solution. Thereafter, Cellulose-C1Ac was used for the ATRP of BMA （butyl methaerylate） mediated by the FeC12/four-dimethyl aminopyridine （DMAP） catalytic system. Acylation reaction and grafting polymerization conditions, such as reaction time, reaction temperature and ratio of reactants were investigated. The hydrophobicity of Cellulose-g-PBMA copolymer was studied with contact angle measurements. Cellulose-CIAc and Cellulose-g-PBMA were characterized by means of FTIR, NMR, SEM, TEM, AFM. Gel permeation chromatography （GPC） was used to analyze the characteristics of the activity of polymerization.