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滇池沉积物生物有效性氮和磷的分布及相互关系
  • 期刊名称:环境科学研究
  • 时间:0
  • 页码:993-998
  • 分类:X524[环境科学与工程—环境工程]
  • 作者机构:[1]中国科学院地球化学研究所,环境地球化学国家重点实验室,贵州贵阳550002, [2]中国科学院研究生院,北京100049, [3]中国环境科学研究院,国家环境保护湖泊污染控制重点实验室,北京100012
  • 相关基金:国家重点基础研究发展计划(973)项目(2008CB418000); 国家自然科学基金项目(U0833603 40903052)
  • 相关项目:滇池营养物质循环与生命过程的耦合关系及蓝藻水华控制机理研究
中文摘要:

利用化学连续提取法,对滇池8个采样点表层沉积物中的生物有效性氮和磷的分布进行了研究,并探讨了二者间的关系.结果表明:滇池沉积物中w(TN)和w(TP)的分布特征具有显著差异,北部和南部因磷矿开采、外源污染输入导致其值较高,中部受水动力影响较大则其值相对较低;沉积物中生物有效性氮和磷包括离子交换态氮和磷(IEF-N,IEF-P)、弱酸可提取态氮和磷(WAEF-N,WAEF-P)、强碱可提取态氮和磷(SAEF-N,SAEF-P)以及强氧化剂可提取态氮和磷(SOEF-N,SOEF-P)等4种形态;各生物有效性氮对总的生物有效性氮的贡献顺序依次为w(SOEF-N)(68.1%~78.8%)〉w(IEF-N)(10.1%~14.9%)〉w(WAEF-N)(5.8%~8.9%)≈w(SAEF-N)(5.3%~8.7%),生物有效性磷的相对含量顺序依次为w(SAEF-P)(68.6%~75.2%)〉w(SOEF-P)(23.4%~30.0%)〉w(WAEF-P)(0.6%~1.8%)〉w(IEF-P)(0~0.1%);生物有效性氮和磷具有正相关性,二者迁移转化的趋势可能具有一致性.生物有效性氮和磷的比值分析表明,沉积物中生物有效性氮和磷的形态差异影响氮、磷的矿化和释放速率.

英文摘要:

The distribution of bioavailable nitrogen and phosphorus forms in eight sampling sites from surface sediments of Dianchi Lake was analyzed by chemical sequential extraction methods,and their relationships were also discussed. The results showed that the distribution of w(TP) and w(TN) varied significantly by spatial location. Due to mining of phosphorite and external pollution inputs, the contents of TP and TN were high in the northern and southern parts of Dianchi Lake. In the middle part,the contents of TP and TN were relatively low because of the influence of hydrodynamic force. The bioavailable nitrogen and phosphorus in the sediments consisted of four forms: ion exchangeable nitrogen and phosphorus (IEF-N,IEF-P),weak acid extractable nitrogen and phosphorus (WAEF-N, WAEF-P),strong alkali extractable nitrogen and phosphorus ( SAEF-N,SAEF-P),and strong oxidant extractable nitrogen and phosphorus (SOEF-N,SOEF-P). The relative contents of different bioavailable nitrogen and phosphorus forms ranked according to the following sequence: w ( SOEF-N ) ( 68. 1%-78. 8% ) w ( IEF-N ) ( 10. 1%-14. 9% ) w ( WAEF-N ) ( 5. 8%-8. 9% ) ≈ w(SAEF-N) (5. 3%-8. 7% ),and w( SAEF-P) (68. 6%-75. 2% ) w( SOEF-P) (23. 4%-30. 0% ) w( WAEF-P) (0. 6%-1. 8% ) w ( IEF-P ) (0-0. 1% ). There was a positive correlation between bioavailable nitrogen and phosphorus forms, indicating the same trend of transfer and transformation. The ratio of bioavailable nitrogen to phosphorus in the same extractant was also analyzed; the results suggested that the different bioavailable nitrogen and phosphorus forms influenced the mineralization and release rate of nitrogen and phosphorus in the sediments.

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