利用中温水热技术合成了新型锰支撑磷钼多金属氧酸盐超分子化合物(H2en)8·[-MnMo12O30(PO4)2(HPO4)6]·H2O,并采用元素分析、红外光谱、热重分析和X射线单晶衍射对其进行了表征.结果表明:该化合物属于三斜晶系,P=1空间群;晶胞参数a=1.2767nm,b=1.3625NM,c=1.4124nm,α=100.550°,β=109.005°,γ=115.398°,V=1.9429nm^2,Z=1,R1=0.0495,wR2=0.1342.
A supermolecular compound, (H2en)8·[-MnMo12O30(PO4)2(HPO4)6]·H2O, was first prepared by hydrothermal synthesis and characterized by elemental analysis, IR, TGA-DSC and single crystal X-ray diffraction. Crystal data.-triclinic, space group P-1 a=1.2767nm,b=1.3625NM,c=1.4124nm,α=100.550°,β=109.005°,γ=115.398°,V=1.9429nm^2,Z=1,R1=0.0495,wR2=0.1342.