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中文摘要：
羟基苯并菲[TP（OH）（OR）5]是一类重要的盘状液晶中间体.根据苯并菲衍生物间极性差异,设计了一条简便的合成与分离羟基苯并菲的方法：在70%硫酸中用FeCl3氧化邻苯二醚与2-甲氧基苯酚三聚成环,分离获得2,3,6,7,10,11-六烷氧基苯并菲[TP（OR）6]和2-羟基-3-甲氧基-6,7,10,11-四烷氧基苯并菲[TP（OH）（OMe）（OR）4].后者再经醚化,Ph2PLi脱甲基得2-羟基-3,6,7,10,11-五烷氧基苯并菲[TP（OH）（OR）5].三步反应总收率14%～19%.
英文摘要：
Monohydroxytriphenylene [TP（OH）（OR）5] is an important intermediate for functionalized or polymeric discotic liquid crystals. Based on the polarity difference among triphenylene derivatives, a new simple method was designed to synthesize monohydroxytriphenylene [TP（OH）（OR）5]： oxidative trimeriza- tion of 1,2-dialkoxybenzene and 2-methoxyphenol by FeC13 in 70% sulfuric acid resulted in 2,3,6,7,10,11-hexa（alkoxy）triphenylene [TP（OR）6] and 2-hydroxy-3-methoxy-6,7,10,11-tetra（alkoxy）triphenylene [TP（OH）- （OMe）（OR）4], then alkylation with RBr and demethylation with Ph2PLi afforded the title compounds. The total yield of the three steps was in the range of 14%- 19%.
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