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粉煤灰联产新型活性硅酸钙作为造纸填料的可行性探讨
  • ISSN号:0254-508X
  • 期刊名称:中国造纸
  • 时间:2012.12.15
  • 页码:27-31
  • 分类:TS753.9[轻工技术与工程—制浆造纸工程]
  • 作者机构:[1]陕西科技大学,陕西西安710021
  • 相关基金:本课题由国家自然科学基金(项目编号:31170560)和陕西科技大学研究生创新基金资助.
  • 相关项目:多孔硅酸钙高加填纸张纤维结合及强度形成机理研究
中文摘要:

研究了粉煤灰联产新型活性硅酸钙填料的填料性能及其作为填料在纸张中的加填性能,探讨了活性硅酸钙不同加填量对纸张性能的影响,并与商品轻质碳酸钙(PCC)填料进行了对比。结果表明,活性硅酸钙粒子呈蜂窝状,具有多孔性,比表面积较大,平均粒径为10.63μm,吸油值为2.178g/g,沉降体积为4.OmL/(10g·24h),白度为90.5%,较适于作为造纸填料。活性硅酸钙加填纸性能检测发现,随着活性硅酸钙用量的增加,纸张白度和不透明度都有较大程度的提高,纸张的抗张指数有较大降低,加填量不超过30%时,撕裂指数基本上保持不变。与商品PCC相比,加填量均为30%时,纸张白度和抗张指数基本相当,不透明度低5.1个百分点,撕裂指数高1.3mN·m2/g,从加填后纸张的SEM图可以看出,活性硅酸钙与纤维之间有较好的交织。

英文摘要:

In this paper, the properties of calcium silicate generated from fly ash and its effect on the paper property when it was used as pa- per filler were investigated. The results were compared with those from PCC- filled sheets under the same conditions. Scanning electronic mi- croscopic observation revealed that the particles of CaSiO3 generated from fly ash had a honeycomb pattern, which was responsible for their highly porous surface structure and high specific surface area. The average diameter of the particles was 10.63 Ixm, the oil-absorbed value was 2. 178 g/g, the sediment volume was 4.0 mL/( 10 g'24 h) , and the brightness was 90.5% , which proved to be suitable for use as pa- per filler. The results showed that with the increasing content of the CaSiO3 , the paper had higher opacity and higher brightness, but lower tensile strength, tearing strength almost unchanged when CaSiO3 content was no more than 30%. When the dosages of fillers were 30%, compared with the papers loaded with PCC, the brightness and tensile of the paper loaded with CaSiO3 were almost the same, while the opac- ity was 5.1% lower and tearing index was 1.3 mN .m2/g higher. SEM photo of the paper loaded with CaSiO3 showed the fibers were well in- tertwined with CaSiO2.

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期刊信息
  • 《中国造纸》
  • 北大核心期刊(2011版)
  • 主管单位:中国轻工业联合会
  • 主办单位:中国造纸学会 中国制浆造纸研究院
  • 主编:邝仕均
  • 地址:北京市朝阳区启阳路4号院2号楼
  • 邮编:100020
  • 邮箱:cpp2108@vip.163.com
  • 电话:010-64778158 64778159
  • 国际标准刊号:ISSN:0254-508X
  • 国内统一刊号:ISSN:11-1967/TS
  • 邮发代号:2-194
  • 获奖情况:
  • 中文核心期刊,中国科技论文统计源期刊,中国科学文献评价数据来源期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:10308