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利用软模板和紫外光固化技术制备超疏水表面
  • ISSN号:1000-3304
  • 期刊名称:《高分子学报》
  • 时间:0
  • 分类:TQ325.306[化学工程—合成树脂塑料工业] Q512.101[生物学—生物化学]
  • 作者机构:[1]清华大学化工系高分子研究所教育部先进材料重点实验室,北京100084
  • 相关基金:国家自然科学基金(基金号20374033,50533040)资助项目
中文摘要:

研究了一种制备超疏水表面的新方法。该方法以复制了荷叶表面结构的聚二甲基硅氧烷(PDMS)弹性体为软模板。利用可紫外光交联预聚物在模板压印条件下固化成型,得到了具有微乳突结构的仿荷叶表面。制备的仿荷叶表面表现出了超疏水性能。通过对紫外光固化体系中的单体含量、交联剂含量、引发剂含量、以及紫外曝光时间等因素的研究,得到了使仿荷叶表面的疏水性优化的条件。

英文摘要:

Super-hydrophobic surfaces have attracted great research interest due to their novel performance as selfcleaning, anti-fog, and anti-oxidation. In this work, a new approach, based on elastomeric templates and UV-curable resins, has been developed to prepare super-hydrophobic surfaces. Poly(dimethylsiloxane) (PDMS, Sylgard 184) was purchased from Dow Coming and used to replicate lotus-leaf surfaces. In the replication step, PDMS blocks were prepared through replica molding against lotus-leaf surfaces. PDMS prepolymer was prepared by mixing the elastomer base and curing agent in a ratio of 10:1. After 20 min, the PDMS prepolymer was poured into molds within freshlotus-leaf surfaces as masters.Then the prepolymer was cured in 40℃ oven for 4 h.After curing and peeling off, the PDMS blocks with negative lotus-leaf surfaces' structures were obtained. Microscope observation indicates that the PDMS blocks' surfaces were featured with hollow cavities of 7 - 12 microns in diameter. The PDMS blocks could be used as stamps in the following curing step of ultraviolet (UV)-curable prepolymers, which consist of oligomer, crosslinking agent, reactive monomer, and photo-initiator. In the experiment, isoboruyl acrylate, siliconized urethane acrylate, benzoin dimethyl ether and dipentaerythritol pentaacrylate were used as monomer, oligomer, photoinitiator and crosslinking agent, respectively. In a typical process, UV-curable prepolymer was prepared by mixing monomer, oligomer, photoinitiator and c rosslinking agent in a ratio of 10:68:2:20. Then the prepolymer was put into a 0.085 MPa vacuum oven to remove air bubble. The prepolymer was spread on substrates ( silicon wafer or glass slide),pressed by the PDMS stamp with replicated lotus-leaf surface. Finally, the UV-curable prepolymer covered with the PDMS stamp was exposed to UV-light (500 μW/cm^2) .After curing for 15 min,the PDMS stamp was peeled off,and the cured sample was store in 40℃ oven for 5 h before further experiments. Measured by sca

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期刊信息
  • 《高分子学报》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国化学会 中国科学院化学研究所
  • 主编:张希
  • 地址:北京市海淀区中关村北一街2号
  • 邮编:100190
  • 邮箱:gfzxb@iccas.ac.cn
  • 电话:010-62588927
  • 国际标准刊号:ISSN:1000-3304
  • 国内统一刊号:ISSN:11-1857/O6
  • 邮发代号:2-498
  • 获奖情况:
  • 国家优秀期刊二等奖,中科院优秀期刊二等奖,中国科协优秀期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国科学引文索引(扩展库),英国高分子图书馆,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:19174