在空穴传输层N,N'-diphenyl—N,N’-bis-1-naphthyl-(1,1’-biphenyl)-4,4’-diamine(NPB)中掺杂电子传输材料Aluminium-tris-8-hydroxy-quinoline(Alqs)制备了有机电致发光器件。当掺杂浓度低于5%时器件仍为蓝光发射,但与同等结构没有掺杂的器件相比,蓝光器件的亮度提高了近20%,达到了12460cd/m^2,外量子效率提高了15.5%。随着掺杂浓度的增加,光谱发生了从蓝光到绿光的红移,这种掺杂方案能够改善空穴和电子的注入平衡,使得空穴和电子在发光层中能够有效地复合,器件的色度、亮度和效率都有了相应的改变。
We have fabricated the organic light-emitting devices(OLEDs) by introducing the electron transmission material aluminium-tris-8-hydroxy-quinoline(Alq3)into hole transport layer N, N'-diphenyl-N, N' -bis- 1-naphthyl- ( 1,1' -biphenyl )-4,4'-diamine (NPB), whose doped concentration affects both color and efficiency of the devices. The OLED is still blue emission when the doped concentration of Alq3is below 5%, compared to the blue devices with a same structure, the brightness increases nearly 20%, up to 12460 cd/m^2, and quantum efficiency increases 15.5 %. The spectrum shifts from blue into green with increasing the doped concentration. The maximum efficiency and luminance of devices are all improved.