以丙烯腈改性的玉米秸秆为吸附剂,对水体中的Cu^2+,Pb^2+,Cd^2+进行吸附,用双组分竞争模型和LCA模型对实验结果进行拟合.结果表明:改性玉米秸秆对三种重金属离子的吸附能很好地符合Langmuir方程,相关性(R^2)分别为0.98,0.95和0.98,最大吸附容量分别为9.34,31.8和12.7mg·g^-1;在Cu^2+和Pb^2+存在下,改性玉米秸秆对Cd^2+的吸附受到明显的抑制,且随Cu^2+和Pb^2+浓度的增大抑制作用加强;在低浓度时,该吸附材料优先吸附顺序为:Cu^2+〉Pb^2+〉Cd^2+高浓度时为:Pb^2+〉Cu^2+〉Cd^2+.
In this experiment, corn stalk modified by acrylonitrile was used to adsorb Cu^2+, Pb^2+ and Cd^2+ inaqueous solution. Two different models, Langmuir competitive adsorption (LCA) and two-component competitive models were employed to describe the adsorption process. The results showed that adsorption of heavy metals by modified corn stalk was fit the Langmuir's equation completely, and R^2 were larger than 0. 95,and the absorption maximum were 9.34, 31.8mg · g^-1 and 12. 73mg · g^-1 respectively for above three metals. The adsorption capacity of Cd^2+ was markedly restrained with the concentration of Cu^2+ and Pb^2+ in solution. According to the equilibrium competitive coefficients, the adsorption sequence of modified corn stalk was Cu^2+ , Pb^2+and Cd^2+.