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宪塘盆地二叠系白云岩油苗地球化学特征及意义
  • ISSN号:1000-0550
  • 期刊名称:《沉积学报》
  • 时间:0
  • 分类:P618.13[天文地球—矿床学;天文地球—地质学]
  • 作者机构:[1]中国地质调查局成都地质调查中心,成都610081, [2]国土资源部沉积盆地与油气资源重点实验室,成都610081
  • 相关基金:中国地质调查局项目(DD20160159,1212011221114,GZH201400301);国家自然科学基金(41172098)
中文摘要:

通过采集羌塘盆地中央隆起带二叠系展金组白云岩油苗及烃源岩样品,对其族组成、饱和烃、芳烃色谱—质谱以及单体碳同位素进行了研究,并进行了油源对比。研究结果表明:白云岩油苗中饱和烃含量最高,其次为非烃,芳烃和沥青质含量较低,饱芳比大于1;白云岩油苗的正构烷烃主要为前高单峰型分布特征,碳数分布范围nC15~nC36,主峰碳为nC17~nC20,nC21-/nC22+值为1.0~4.56,C27-C28-C29规则甾烷表现为不规则的“V”型的分布并且C29甾烷占优势,升藿烷从C31~C35均有检出,显示出白云岩油苗的生烃母质主要来源于藻类和细菌等低等水生生物;白云岩油苗的Pr/Ph值为0.91~1.30,伽马蜡烷指数值为0.42~0.88,三芴系列化合物中以硫芴含量最高(平均67.39%)而氧芴含量(平均7.89%)较低,4-MDBT/DBT比值为0.97~4.26,(2+3)-MDBT/DBT 值为0.37~1. 62,表明白云岩油苗生烃母质为形成于具有一定盐度还原环境为的海相页岩;白云岩油苗的OEP值接近平衡值1,甾萜烷异构参数C29ααα20S/ααα(20S+20R)、C29αββ/(ααα+αββ)和C3122S/(22S+22R)等接近或达到平衡值,芳烃标志物成熟度参数MPI1、F1和4,6/1,4-DMDBT计算出的等效镜质体反射率表明白云岩油苗为成熟原油。白云岩油苗的生物标志物和展金组泥岩具有较好对比性,反映了白云岩油苗主要来源于展金组烃源岩;其单体碳同位素与二叠系展金组烃源岩分布形式和变化趋势基本相似,但也有一定的差异,反映了其具有混合来源的特点。

英文摘要:

Dolomite oil seepages and hydrocarbon source rocks of Permian Zhanjin Formation were collected systematically from Central uplift belt area in Qiangtang Basin.Based on the analytical data of group component, biomarkers and carbon isotopic compositions of n-alkanes and isopre, the author analyzed the geochemical characteristics of Permian dolomite oil seepages,and the oil-source rock correlation was also studied in the paper. The results indicated that the Permian dolomite oil seepages are high fraction saturated hydrocarbons,followed by non hydrocarbon, aromatics and asphaltene fraction are low. The ratio of saturates/aromatics of dolomite oil seepages are more than 1.0. The alkanes of dolomite oil seepages are composed of nC15 - nC36,with nC17~nC20 as the main peaks,and characteristics of single peak distribution.The nC21-/nC22+ ratios from 1.0 to 4.56,the regular sterans C27-C28-C29 distributed with irregular “V”shape and predominance of C29,homohopane were detected from C31~C35, indicating dolomite oil seepages of hydrocarbon material sources were in algae and other lower aquatic organisms. The Pr/Ph values range of dolomite oil seepages were between 0.91 to 1.30,and gammacerane/C30hopane values were from 0.42 to 0.88, the content of dibenzothiophene were the highest (average 67.39%) and low dibenzofuran content (average 7.89%). 4-MDBT/DBT values of dolomite oil seepages were 0.97 to 4.26, (2+3)-MDBT/DBT values were 0.37 to 1.62, showing dolomite oil seepages hydrocarbon material sources were formed in marine shale with certain salinity reduction environment. The OEP values, C29ααα20S/ααα (20S+ 20R) values,C29αββ/(ααα+αββ) values and C3122S/(22S+22R) values etc., closed to equilibrium values 1, aromatic maturity parameters MPI1,F1 and 4,6/1,4-DMDBT calculated from the equivalent vitrinite reflectance showed that dolomite oil seepages were mature crude oil. The biomarkers of oil seepages are closely correlated to the Zhanjin Formation black mudstone, reflecti

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期刊信息
  • 《沉积学报》
  • 北大核心期刊(2011版)
  • 主管单位:
  • 主办单位:中国科学院兰州地质研究所 中国矿物岩石地球化学学会沉积学专业委员会 中国地质学会沉积地质专业委员会
  • 主编:刘宝珺
  • 地址:兰州市东岗西路382号
  • 邮编:730000
  • 邮箱:cjxb@ns.lzb.ac.cn
  • 电话:0931-4960916
  • 国际标准刊号:ISSN:1000-0550
  • 国内统一刊号:ISSN:62-1038/P
  • 邮发代号:54-45
  • 获奖情况:
  • 国内外数据库收录:
  • 美国化学文摘(网络版),美国地质文献预评数据库,英国动物学记录,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:24598