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导电聚苯胺电极柱识别天冬氨酸对映体的研究
  • 期刊名称:分析测试学报
  • 时间:0
  • 页码:1176-1179
  • 语言:中文
  • 分类:O641.3[理学—物理化学;理学—化学] Q503[生物学—生物化学]
  • 作者机构:[1]Institute of Petrochemical Technology, Changzhou University, Changzhou, Jiangsu 213164, China
  • 相关基金:Project supported by the National "Natural Science-Foundation of China (No. 20805021), Natural Science Fund for Colleges and Universities in Jiangsu Province (Nos. 10KJB150004, 09KJA430002) and the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).
  • 相关项目:电极式离子色谱柱分离氨基酸光学异构体的研究
作者: 孔泳|
中文摘要:

为在 polyaniline (平底锅) 的 L 丁氨二酸酸(L 毒蛇) 的亲密关系地点被二个连续过程创造:首先, L 毒蛇简单地在苯胺的聚合期间作为模板分子被增加;第二,在平底锅脊梁合并的 L 毒蛇被溶剂提取。有对 L 毒蛇模板分子补足的洞的平底锅为 L 毒蛇和 D 毒蛇的 enantioselective 识别被利用了。印的平底锅的 Enantioselectivity 能在在形状并且在组放对 L 毒蛇模板补足的印的平底锅被归因于洞。另外在这糊,在 L 毒蛇模板的抽取前后的结构的变化被 Fourier 变换揭示红外线(FTIR ) 光谱。

英文摘要:

Affinity sites for L-aspartic acid (L-Asp) in polyaniline (PAn) were created by two successive processes: first, L-Asp was simply added as template molecules during the polymerization of aniline; second, L-Asp incorporated in PAn backbone was extracted by solvent. PAn with cavities complementary to L-Asp template molecules has been utilized for enantioselective recognition of L- and D-Asp. Enantioselectivity of the imprinted PAn could be attributed to the cavities in the imprinted PAn which was complementary to L-Asp templates both in shape and in positioning of groups. Also in this paper, the structural changes before and after extraction of L-Asp templates were revealed by Fourier-transform infrared (FTIR) spectrum.

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