采用水热法在导电玻璃( FTO)上合成具有一维结构的TiO2纳米棒阵列薄膜.用扫描电子显微镜,广角X-射线粉末衍射,紫外可见分光光谱等手段对薄膜进行了表征,研究了不同浓度钛酸四丁酯和水热反应时间对FTO-TiO2纳米棒阵列薄膜形貌的影响及FTO-TiO2纳米棒阵列薄膜光催化还原Cr(Ⅵ)的反应性能.结果表明,当钛酸四丁酯浓度为0.05 mol·L^-1和水热反应时间为20h时制备的FTO?TiO2纳米棒阵列薄膜形貌最优,一维FTO-TiO2纳米棒阵列薄膜光催化还原Cr(Ⅵ)的性能优于商业化二氧化钛 P25制备的薄膜.
One dimensional TiO2 nanorod array films on conductive glass ( FTO) were prepared with a hydrothermal method. The obtained films were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy and UV-vis diffuse reflectance spectroscopy. Influence of tetrabutyl titanate concentration and water thermal reaction time on the morphology of FTO-TiO2 nanorods array films and the photocatalysed reduction of Cr(Ⅵ) using FTO-TiO2 nanorods array films were studied. The results indicated that optimum conditions for preparing optimal morphology of FTO-TiO2 nanorods array films were found as follows:tetrabutyl titanate concentration 0.05 mol·L^-1 and water thermal reaction time 20 h. FTO-TiO2 nanorod array films performed much better in photocatalysed reduction of Cr(Ⅵ) than the commercial P25 films.