中文摘要：

建立了蔬菜和水果中11种三唑类农药残留的气相色谱-质谱（GC—MS）测定方法。样品用乙腈均质提取，经石墨化炭黑／氨基复合柱净化，乙腈-甲苯（3：1）洗脱。洗脱液经浓缩、溶剂交换后定容，采用气相色谱-质谱的选择离子监测方式（GC—MSD／SIM）进行测定，内标法定量。方法的线性范围为0．05—5ng，相关系数为0．996—1．000，对甘蓝、番茄、苹果、柑橘、菠菜5种空白基质分别进行0．01、0．05、0．10mg／k3个水平加标，平均回收率为80％～97％，相对标准偏差（RSD，n=10）为2．5％～8．4％。11种农药的检出限均为0．01mg／kg。该方法操作简单，灵敏度高，结果准确可靠。

英文摘要：

A method was developed for the determination of 11 triazole pesticides residues in fruits and vegetables using gas chromatography -mass spectrometry（ GC -MS）. The samples were homogemethod. The calibration curves of 11 triazole pesticides were linear in the range of 0.05 - 5 ng with correlation coefficients of 0. 996 - 1. 000. The spiked recoveries of 11 triazole pesticides from five matrices（ e, g. cabbage, tomato, apple, orange, spinach ） at three spiked levels of 0. 01, 0. 05, 0. 10 mg/kg were in the range of 80% - 97% with relative standard deviations （ RSDs, n = 10） of 2.5% -8.4%. The limits of detection were 0.01 mg/kg for 11 triazole pesticides. The method is simple, sensitive, accurate and reliable.