设计合成了以罗丹明为母体的探针分子RCu,可实现对Cu^2+的选择性识别。在HEPES缓冲溶液(2×10^-5mol·L^-1,p H=7.4)的测试体系中RCu本身无颜色,加入Cu^2+后溶液变为粉红色,而且加入其他常见金属阳离子无颜色变化。探针分子可识别较低浓度的Cu^2+,检出限可达6.37×10^-8 mol·L^-1。同时探针分子可用于试纸化检测,对水样中的Cu^2+可实现低浓度的检测,具有一定的实用价值。
A new Rhodamine derivative RCu was designed and synthesized as a colorimetric probe for Cu(Ⅱ) with high selectivity. RCu itself has no color in HEPES buffer solution(2×10^-5 mol·L^-1, p H = 7.4). With Cu^2+added, the solution turns into pink color, but without change in color with other common metal cations. The probe can recognize Cu^2+ at low concentrations and the detection limit is 6.37×10^-8 mol·L^-1. Meanwhile, the probe can detect Cu^2+ in water samples at lower concentrations by indicator paper, indicative of its great potential applications.