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中文摘要：
通过MnⅢnaphtmen H2O2ClO4（H2naphtmen=N,N＇-二（2-羟基-1-萘甲醛）缩（1,1,2,2-四甲基乙二胺））和Li（TCNQ）（TCNQ=7,7,8,8-四氰基对苯二醌二甲烷自由基阴离子）反应,合成了一个中心对称的双氧桥联双核锰配合物MnⅣnaphtmen-O2（1）.单晶X-射线衍射结果表明,配合物1属单斜晶系,2（1）/c空间群,a=13.277（3）,b=10.066（2）,c=16.960（3）,β=97.28（3）°,V=2 248.2（8）3,Z=4,F（000）=760,μ=0.622 mm1,1=0.0438,w R2=0.112 2.中心Mn（Ⅳ）离子采取变形八面体的配位构型,分子内MnMn距离为2.7591,桥联键角Mn-O-Mn为99.36°.变温磁化率研究表明,配合物1双核单元内Mn（Ⅳ）离子间存在着弱的反铁磁相互作用：J=0.19 cm1,g=2.02.
英文摘要：
One centrosymmetric di-μ-oxo dimanganese （IV） complex [MnW（naphtmen）（μ-O）]2 （1） was synthesized based on the reaction of [Mnm（naphtmen）（H2O）2]ClO4 （H2naphtmen = N, N＇-bis （2-hydroxy-l-naphthalidene） -1,1,2,2- tetramethyl-1,2- diaminoethane） and Li （TCNQ） （TCNQ.- = 7, 7, 8, 8-tetracyanoquinodimethane radical monoanion）. The X-ray single-crystal diffraction analysis shows that complex 1 crystallizes in space group P2 （I） /c with a = 13.277 （3） , b=10.066 （2） ,, c=16.960 （3） , β=97.28 （3） ° , V=2248.2 （8） 3, Z=4, F （000） =760, μ= 0.622 mm^-1, R1= 0.043 8 and wR2 = 0.112 2. The coordination polyhedron of each Mn （IV） ion can be described as a distorted octahedron. The intramolecular Mn-Mn distance is 2.7591 and the Mn-O-Mn angle is 99.36°. The temperaturedependent effective magnetic moment of complex 1 indicates that a weak intramolecular antiferromagnetic interaction between the two manganese （IV） ions （d3） exists. The best fit has given the parameters： J= -0.19 cm^-1, g = 2.02. Key words di-μ-oxo dimanganese （IV） complex; tetradentate Schiffbase; crystal structure; magnetic property
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