本文在合成水溶性巯基乙酸修饰的CdTe量子点的基础上,研究了CdTe量子点与罗丹明6G之间的荧光共振能量转移。实验结果表明:构建的CdTe量子点(供体)-罗丹明6G(受体)荧光共振能量转移体系在磷酸盐缓冲溶液中有较好的转移效果。当磷酸缓冲溶液pH值为7.4,NaCl浓度为1.0mol/L时,构建的CdTe量子点-罗丹明6G荧光共振能量转移效率为62%;罗丹明6G既能与CdTe量子点表面的修饰试剂作用,也能与CdTe量子点本身直接作用,其作用力为静电相互作用和配位作用。
CdTe quantum dots(QDs) were synthesized in aqueous medium by employing thioglycolic acid as a stabilizer.The fluorescence resonance energy transfer(FRET) between CdTe QDs and rhodamine 6G(Rh 6G) was investigated.The results showed that the energy transfer efficiency was 62% at pH=7.4 in 1.0 mol/L NaCl.Rh 6G molecules interacted not only with thioglycolic acid but also with the surface of CdTe QDs directly.The forces of the interaction were electrostatic interaction and coordinate interaction.