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近红外光谱法同时测定盐酸氯丙嗪和盐酸异丙嗪
  • ISSN号：1006-6144
  • 期刊名称：分析科学学报
  • 时间：2013
  • 页码：61-64
  • 分类：O657.33[理学—分析化学;理学—化学]
  • 作者机构：[1]长江师范学院化学化工学院,重庆涪陵408100, [2]西南大学化学化工学院,重庆北碚400715, [3]三峡学院化学化工学院,重庆万州404000
  • 相关基金：国家自然科学基金（No.21175015）;重庆涪陵区科委攻关项目（No.2011ABA2028）;涪陵区科委项目（FLKJ,2011AAA2006）;重庆市高校科研创新团队
  • 相关项目：共振瑞利散射光谱法对有机对映体的手性识别研究
作者： 周尚|吴利敏|朱乾华|杨季冬|
关键词： 近红外光谱法, 偏最小二乘法, 盐酸氯丙嗪, 盐酸异丙嗪, Near-infrared spectroscopy, Partial least square method, Chlorpromazine hydrochloride, Promethazine hydrochloride
中文摘要：

采用近红外光谱法同时测定盐酸氯丙嗪和盐酸异丙嗪。对光谱经过10种不同预处理后，分别建立了测定盐酸氯丙嗪和盐酸异丙嗪的PLS校正模型。根据模型评价参数选择最佳模型，并用该模型对未知样品进行了预测。结果显示，对浓度范围在1～13mg·mL-1的盐酸氯丙嗪和盐酸异丙嗪，其近红外的最佳数学模型的相关系数分别为0．9432和0．9670，预测模型的均方根误差（RMSEP）分别为1．05和1．11。

英文摘要：

The chlorpromazine hydrochloride and promethazine hydrochloride in aqueous solution were studied by near infrared spectroscopy. The partial least square mathematical models for simultaneous determination of chlorpromazine hydrochloride and promethazine hydrochloride were built after 10 times spectrum pretreatment. The best models were selected according to the model evaluation parameters, and unknown samples were predicted. Under the concentration range of 1-13 mg· mL 1, correlation coefficients of the best models were 0. 9432 for chlorpromazine hydrochloride and 0. 9670 for promethazine hydrochloride,and the root mean square error of prediction（RMSEP） were 1.05 and 1.11, respectively.

同期刊论文项目
共振瑞利散射光谱法对有机对映体的手性识别研究
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期刊信息
  • 《分析科学学报》
  • 中国科技核心期刊
  • 主管单位:教育部
  • 主办单位:武汉大学 北京大学 南京大学
  • 主编：程介克
  • 地址：湖北武昌武汉大学化学学院
  • 邮编：430072
  • 邮箱：
  • 电话：027-68752248
  • 国际标准刊号：ISSN：1006-6144
  • 国内统一刊号：ISSN：42-1338/O
  • 邮发代号:38-202
  • 获奖情况:
  • 中文核心期刊,教育部优秀期刊
  • 国内外数据库收录:
  • 美国化学文摘（网络版）,美国剑桥科学文摘,中国中国科技核心期刊,中国北大核心期刊（2008版）,中国北大核心期刊（2011版）,中国北大核心期刊（2014版）,英国英国皇家化学学会文摘,中国北大核心期刊（2000版）
  • 被引量:12943