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炭黑表面活性对填料网络和填料与橡胶之间相互作用的影响
  • 期刊名称:华东理工大学学报(自然科学版),2008, 34(5): 684-687
  • 时间:0
  • 分类:TQ330.3[化学工程—橡胶工业]
  • 作者机构:[1]华东理工大学材料科学与工程学院高分子合金研究室,上海200237
  • 相关基金:国家自然科学基金重点项目(50733001)
  • 相关项目:纳米炭黑复合粒子填充法制备柔韧性透明导电薄膜的基础研究
中文摘要:

采用原位固相接枝技术,将天然橡胶大分子接枝到炭黑表面,并考察了炭黑表面活性对其填充天然橡胶中填料网络和填料与橡胶相互作用程度的影响。结果表明:炭黑经过接枝改性后,其表面活性增加,且与橡胶基体的相互作用力增大,炭黑之间的网络化程度降低。

英文摘要:

Nature rubber was grafted on the surface of carbon black (CB) to modify the surface activity of CB via the in situ solid state grafting. Results of bound rubber showed that the surface activity of grafted CB was increased. Influences of the surface activity of CB on the strength of filler network and the filler-rubber interaction were investigated with rubber-process-analyzer (RPA) and dynamic mechanical analysis (DMA). Results showed that compared with the system filled with original CB, the filler-rubber interaction was enhanced and the strength of filler network was decreased for the system filled with grafted CB.

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