以对叔丁基杯[4]芳烃为原料,通过醚化、原位硝化、还原、缩合四步反应合成了三个新型的具有1,3-交替构象的杯芳烃-香豆素衍生物,其结构经1H NMR,13C NMR,IR和MS表征。
Three novel calix[4]arene derivatives bearing four coumarin units in 1,3-alternate conformation were prepared from p-tert-butylcalix[4]arene by etherification,ipso-nitration,reduction,condensation reaction.The structures were characterized by 1H NMR,13C NMR,IR and MS.