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溶胶-凝胶法制备NASICON型Li1.15Y0.15Zr1.85（PO4）3固态电解质
  • ISSN号：0454-5648
  • 期刊名称：《硅酸盐学报》
  • 时间：0
  • 分类：TQ174.75[化学工程—陶瓷工业;化学工程—硅酸盐工业] TM912[电气工程—电力电子与电力传动]
  • 作者机构：[1]景德镇陶瓷学院材料科学与工程学院, [2]清华大学材料学院新型陶瓷与精细工艺国家重点实验室
  • 相关基金：创新研究群体科学基金(51221291)资助项目
作者： 刘美景[1,2], 魏红康[1], 李玉涛[2], 汪长安[2]
关键词： 溶胶-凝胶法, 固态电解质, 离子电导率
中文摘要：

以碳酸锂、硝酸锆、磷酸氢二铵和硝酸钇为原料,柠檬酸为络合剂,采用溶胶–凝胶法制备了NASICON型Li1.15Y0.15Zr1.85(PO4)3固态电解质材料,通过无压烧结和放电等离子烧结(SPS)得到固态电解质片。结果表明:采用无压烧结在1 150℃制备的电解质密度可以达到理论密度的95.2%,在室温下晶粒电导率和总电导率分别为2.19×10–4 S/cm和0.86×10–4 S/cm;采用SPS在1 150℃烧结得到的电解质片密度可达到理论密度的96.8%,在室温下样品总电导为0.97×10–4S/cm,激活能为0.44 e V。四方相Zr O2的存在是样品激活能升高的主要原因。

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期刊信息
  • 《硅酸盐学报》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:中国硅酸盐学会
  • 主编：南策文
  • 地址：北京海淀区三里河路11号
  • 邮编：100831
  • 邮箱：jccsoc@sina.com
  • 电话：010-57811253 57811254
  • 国际标准刊号：ISSN：0454-5648
  • 国内统一刊号：ISSN：11-2310/TQ
  • 邮发代号:2-695
  • 获奖情况:
  • EI　Compendex、CA、SA、PI收录期刊,全国核心期刊,中国期刊方阵“双效”期刊
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  • 被引量:27713