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MgH2反应法制备Mg2(Sn,Si)基热电材料及性能研究
  • ISSN号:1674-0785
  • 期刊名称:《中华临床医师杂志(电子版)》
  • 时间:0
  • 分类:TB34[一般工业技术—材料科学与工程]
  • 作者机构:[1]山西景辉新能源技术公司,太原030024, [2]太原理工大学材料科学与工程学院,太原030024
  • 相关基金:山西省归国留学人员资助项目(2012-033)
中文摘要:

采用MgH2与Sn粉、Si粉通过固相反应法结合FAPAS法,实现了Mg2(Sn,Si)基热电材料的制备及快速致密化。采用MgH:代替单质Mg粉与Sn粉、Si粉为原料进行固相反应可有效避免Mg单质的挥发和氧化。相较于纯Mg2Sn和纯Mg:Si样品,Mg2(Sn,Si)系列固溶体热导率显著降低,但同时电性能也有所下降,样品在500K时获得最佳zT值,其中Mg2Si0.5Sn0.5样品的ZT值最高,在500K时达到0.18.MgH,反应法由于反应温度低,容易实现,产品晶粒尺寸小,热电性能佳,对于制备Mg-Si体系热电材料有很大的优势。

英文摘要:

Mg2 (Sn, Si)-based thermoelectric (TE) materials was prepared by a solid-state reaction between MgH2 and Sn powder and Si powder by a field-activated and pressure-assisted sintering process (FAPAS) in order to re- alize rapid densification. Reaction between Sn or Si powder and magnesium hydride instead of pure magnesium minimizes the oxidation and volatilization of magnesium. The thermal conductivity of Mg2 (Si, Sn) sosoloid was significantly lower than that of pure Mg2 Si and pure Mg2 Sn samples, but the electrical properties were also de- creased, and the optimum ZT value was obtained at 500K. Among them, the ZT value of Mg2Sio.5 Sn0.5 was the highest and reached 0.18. The MgH2 reaction method is easy to realize because of its lower reaction temperature. The grain size of the product was small and the thermoelectric properties were good. There is a great advantage in the preparation of Mg-Si system materials. The thermal conductivity was greatly reduced by the formation of Mg2 (Sn, Si) sosoloid.

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期刊信息
  • 《中华临床医师杂志(电子版)》
  • 主管单位:
  • 主办单位:中华医学会
  • 主编:
  • 地址:北京市西直门北大街32号B座606C室
  • 邮编:100082
  • 邮箱:lcdoctor@163.com
  • 电话:010-62219211
  • 国际标准刊号:ISSN:1674-0785
  • 国内统一刊号:ISSN:11-9147/R
  • 邮发代号:
  • 获奖情况:
  • 国内外数据库收录:
  • 美国化学文摘(网络版),波兰哥白尼索引
  • 被引量:30430