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La0.6Sr0.4Co0.2Fe0.8O3-δ-Gd0.1Ce0.9O1.95复相材料的性能
  • ISSN号:0454-5648
  • 期刊名称:《硅酸盐学报》
  • 时间:0
  • 分类:TQ174.758[化学工程—陶瓷工业;化学工程—硅酸盐工业] TM911.4[电气工程—电力电子与电力传动]
  • 作者机构:[1]Union Research Center of Fuel Cell, School of Chemical and Environmental Engineering, China University of Mining and Technology. Beijing 100083, China, [2]State Key Laboratory of PowerSystems, Department of Thermal Engineering, Tsinghua University, Beijing 100084, China
  • 相关基金:Acknowledgments The authors gratefully acknowledge the financial support from the National Basic Research Program of China (973 Program, No. 2012CB215404), the National Natural Science Foundation of China (Nos. 51261120378 and 51402355), Beijing Natural Science Foun- dation (No. 2154056) and Specialized Research Fund for the Doctoral Program of Higher Education (SRFDP, No. 20130023120023).
中文摘要:

在这个工作,一个管状的陶器支持的稳固的氧化物燃料房间(SOFC ) 被包含阶段倒置,刷子涂层和泉华 co 的低费用和简单过程成功地制作。包括 sintering 行为,管状的支持的微观结构以及单个房间的电气化学的性质的性质被调查。结果证明有指状的毛孔和 macrovoids 的多孔的管状的支持在阶段倒置过程以后被获得。管状的支持被证明在在 1400 点的 sintering 以后气体可渗透吗??

英文摘要:

In this work, a tubular ceramic-supported solid oxide fuel cell (SOFC) was successfully fabricated by a low cost and simple process involving phase-inversion, brush coating and co-sintering. Properties in- cluding sintering behavior, microstructure of the tubular support as well as the electrochemical properties of single cell were investigated. The results show that a porous tubular support with finger-like pores and macrovoids was obtained after phase-inversion process. The tubular support is proved to be gaspermeable after sintering at 1400 ℃ with shrinkage of about 34%. The maximum power density of single tubular SOFC is 100 mW/cm2 and 122 mW/cm2 at 850 ℃ when fed with wet methane and hydrogen, respectively. The current collection, thickness of electrolyte and gas permeability of tubular support should account for the large total resistance. The present tubular design could be expected to deliver a higher voltage for longer support with several segmented-in-series cell stacks.

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期刊信息
  • 《硅酸盐学报》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:中国硅酸盐学会
  • 主编:南策文
  • 地址:北京海淀区三里河路11号
  • 邮编:100831
  • 邮箱:jccsoc@sina.com
  • 电话:010-57811253 57811254
  • 国际标准刊号:ISSN:0454-5648
  • 国内统一刊号:ISSN:11-2310/TQ
  • 邮发代号:2-695
  • 获奖情况:
  • EI Compendex、CA、SA、PI收录期刊,全国核心期刊,中国期刊方阵“双效”期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:27713