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Pt-Rh型三效催化剂中BaO的作用
  • 期刊名称:中国稀土学报,2006.2,24(1),27-31
  • 时间:0
  • 分类:O643.3[理学—物理化学;理学—化学]
  • 作者机构:[1]四川大学化学学院,四川成都610064
  • 相关基金:国家自然科学重点基金(20333030)和国家自然科学基金资助项目(20273043)
  • 相关项目:根据含硫和含氮化合物的本征反应特性构建高效脱硫和脱氮催化反应
中文摘要:

研究了以浸溃法制备的以BaO为助剂的Pt-Rh型三效催化剂对C3H8,CO,NOx的三效催化活性。主要考察了BaO不同的添加方式对催化剂三效转化活性的影响,并对催化剂样品进行了XRD,H2-TPR和O2-TPD表征。结果表明:BaO的添加方式的不同,直接影响催化剂的活性。特别是Ba与Ce,Zr以共沉淀的方式形成CeO2-ZrO2-BaO固溶体,可促进催化剂在低温时的水汽转换反应,显著降低了催化剂的起燃温度。

英文摘要:

The effect of BaO doping to the Pt-Rh catalysts on its three-way catalytic activity and water-gas transfer was investigated. The results show that the lightoff temperatures of hydrocarbon and carbon monoxide and nitrogen oxides have of little difference in the fresh catalysts. But after hydrothermal-aged 5 h at 1000℃, the catalysts containing CeO2-ZrO2-BaO has lower light-off temperature and better catalytic activity than the catalysts containing BaO and CeO2-ZrO2. The catalysts were characterized by means of temperature-programmed reduction (TPR) in the hydrogen and the temperature-progrmmed desorption (TPD) in oxygen. It is confirmed that the presence of CeO2-ZrO2-BaO by co-precipitation can improve catalytic activity of catalysts.

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