以溴化N-丙基吡啶离子液体为溶剂,在离子热反应条件下,合成了二维磷酸锌化合物Zn2(H2PO4)3(HPO4)2·3C8H12N.X射线单晶结构分析结果表明:该化合物属于正交晶系,Pca21空间群;晶胞参数a=2.257 8(3)nm,b=0.965 6(13)nm,c=1.829 8(2)nm,V=3.989 2(9)nm3,Z=4.
A new layered zinc phosphate,Zn2(H2PO4)3(HPO4)2·3C8H12N was ionothermally prepared using 1-propyl pyridinium bromide as solvent and template.The results of single-crystal X-ray diffraction reveal that this complex crystallizes in the orthorhombic system,space group Pca21,with the parameters of a=2.257 8(3) nm,b=0.965 6(13) nm,c=1.829 8(2) nm,V=3.989 2(9) nm3,Z=4.