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模拟酸雨对工业污染场地表层土壤中多环芳烃释放的影响
  • ISSN号:0254-6108
  • 期刊名称:环境化学
  • 时间:0
  • 页码:497-503
  • 分类:X132[环境科学与工程—环境科学]
  • 作者机构:[1]中国矿业大学(北京)化学与环境工程学院,北京100083, [2]中国环境科学研究院,北京100012, [3]洛阳理工学院环境工程与化学系,洛阳471023, [4]北京科技大学土木与环境工程学院,北京100083
  • 相关基金:国家自然科学基金项目(No.20977088)资助
  • 相关项目:土壤酸化胁迫下有机矿质复合体中疏水性污染物的稳定性
中文摘要:

通过工业污染场地表层土壤的模拟酸雨浸泡试验,分析了不同酸度的模拟酸雨浸泡前后土壤中有机质、EPA优先控制的16种多环芳烃含量和矿物质组成的变化.研究结果表明,酸雨浸泡前后土壤矿物相组成相似,主要以石英为主,只是在矿物组成的量上存在差别,浸泡后土壤中赤铁矿和粘土矿物的含量较浸泡前有所减少.模拟酸雨浸泡后土壤中有机质和多环芳烃均有不同程度的释放,酸雨pH值越小,释放量越大,且多环芳烃可能是随着有机质一起释放的;酸雨对土壤中不同性质多环芳烃释放的影响不同,对低环多环芳烃(环数≤3)释放的影响较大,对高环多环芳烃(环数≥4)影响较小.研究结果为理解在酸雨作用下工业污染场地土壤中多环芳烃的释放规律及土壤中多环芳烃稳定性研究提供一些科学依据.

英文摘要:

A laboratory soaking experiment on topsoils from an industry contaminated site was carried out using simulated acid rain,in which change of soil organic matter(SOM),concentration of polycyclic aromatic hydrocarbons(PAHs) and mineral composition before and after soaking by simulated acid rain were analyzed.The results showed that the soil mineral was found to exhibit similar composition before and after soaking.The main component was quartz.However,the percentage of each mineral component was different,and the hematite and clay mineral decreased after soaking when compared to the original soil.Soil organic matter and polycyclic aromatic hydrocarbons were released from the soil soaked by simulated acid rain,and the release quantity increased with the decrease of acid rain pH.PAHs associated with SOM were released from topsoils under simulated acid rain.The effect of acid rain on the release of different PAHs from topsoils was different.And acid rain had greater influence on the release of low-aromatic ring PAHs(≤3),while its influence was less for high-aromatic ring PAHs(4).The results may help to understand the release pattern of PAHs from topsoils in an industrially contaminated site under acid rain and provide the scientific support for research of PAHs stability in soil under acid rain.

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期刊信息
  • 《环境化学》
  • 北大核心期刊(2011版)
  • 主管单位:中国科学院
  • 主办单位:中国科学院生态环境研究中心
  • 主编:郭良宏
  • 地址:北京2871信箱
  • 邮编:100085
  • 邮箱:hjhx@rcees.ac.cn
  • 电话:010-62923569
  • 国际标准刊号:ISSN:0254-6108
  • 国内统一刊号:ISSN:11-1844/X
  • 邮发代号:82-394
  • 获奖情况:
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:27127