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AM60镁合金锰系磷酸盐转化膜的耐蚀性研究
  • ISSN号:1000-4742
  • 期刊名称:《电镀与环保》
  • 时间:0
  • 分类:TG174[金属学及工艺—金属表面处理;金属学及工艺—金属学]
  • 作者机构:[1]沈阳师范大学化学与生命科学学院,辽宁沈阳110034
  • 相关基金:国家自然科学基金(50971093)资助项目
中文摘要:

通过向锰系磷酸盐溶液中添加促进剂,在AM60镁舍金表面得到了耐蚀性良好的化学转化膜。用电化学方法研究了该转化膜在质量分数为3.5%的NaCl溶液中的腐蚀行为。动电位极化曲线结果表明:转化膜的自腐蚀电位相对于合金基体的大幅正移,自腐蚀电流密度明显减小,但阳极钝化电位区间不很明显。EIS结果表明:转化膜的高频容抗弧曲率半径较合金基体的明显增大。SEM研究表明:转化膜呈结晶态,晶粒排列较为紧凑,无明显裂纹出现。EDX分析表明:转化膜表面含有O,P和Mn等元素。

英文摘要:

A chemical conversion film with good corrosion resistance was obtained on the surface of AM60 magnesium alloy in manganese phosphate bath, to which an accelerant was added. The corrosion behavior of the film in 3.5% NaCl was investigated by electrochemical methods. The dynamic potential polarization curve tests show that the self-corrosion potential of the film shifts positively in large range and the corrosion current density decreases obviously comparing with that of the alloy substrate, however, the passivation potential extent in anodic branch of the polarization curve is not distinct. Electrochemical impedance spectroscopy (EIS) measurement illustrates that the culvature radius of capacitive impedance arc in high frequency is increased significantly comparing with that of the alloy substrate. SEM observation indicates that the film is presented in crystal form and the crystal grains are arranged compactly with no obvious cracks. EDX analysis illustrates that the film surface is composed of oxygen and phosphor as well as manganese.

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期刊信息
  • 《电镀与环保》
  • 北大核心期刊(2011版)
  • 主管单位:中国轻工业联合会
  • 主办单位:上海市轻工业科技情报研究所
  • 主编:孙豪展
  • 地址:上海市余姚路607弄19号
  • 邮编:200042
  • 邮箱:ddyhbmail@163.com ddyhb@online.sh.cn
  • 电话:021-62303415/62318942
  • 国际标准刊号:ISSN:1000-4742
  • 国内统一刊号:ISSN:31-1507/X
  • 邮发代号:4-328
  • 获奖情况:
  • 1992年获中国轻工业部优秀科技期刊一等奖和国家优...,1996年获中国轻工总会优秀科技期刊二等奖和上海市...,中国期刊方阵“双效”期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),中国中国科技核心期刊,中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:5397