中文摘要：

MOF-74 类似物源于 non-DOBDC 连接器， Cu (II )-MOF-74-L¹, 被综合并且描绘。基于这，六角形的毛孔的 directionanl functionalizations 通过 ligands 的设计得好的安装前被介绍。由这策略，有毛孔的恐水病、吸水的表面的二 MOF-74 类似物被与 Cl 装备完成了或哦分别地组织并且与优秀催化作用和光察觉到性质证明了。此处，合成策略和功能的规定向功能的 MOF-74 材料的发展被报导。

英文摘要：

A MOF-74 analog derived from non-DOBDC linkers, Cu（II）-MOF-74-L^1, was synthesized and characterized. Based on this, directionanl functionalizations of the hexagonal pore were introduced through well-designed pre-installation of ligands. By this strategy, two MOF-74 analogs with hydrophobic and hydrophilic surfaces of pore had been achieved by equiping with CI or OH groups respectively and proved with excellent catalysis and luminescent sensing properties. Herein, the synthetic strategy and functional regulation were reported toward the development of functional MOF-74 materials.