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对比研究热浸镀55%Al-Zn镀层与Zn镀层在盐水中的腐蚀机理
  • ISSN号:1001-7208
  • 期刊名称:《上海金属》
  • 时间:0
  • 分类:TG174.443[金属学及工艺—金属表面处理;金属学及工艺—金属学]
  • 作者机构:[1]上海大学材料科学与工程学院,上海200072
  • 相关基金:国家科技支撑计划课题资助(2007BAE09803),贵州省“十一五”重大专项资助(20076003)
中文摘要:

用盐雾腐蚀和浸泡腐蚀两种方法对比研究了热浸镀55%A1一Zn镀层和zn镀层在盐水环境中的腐蚀行为。用光学显微镜和扫描电子显微镜观察了清除腐蚀产物后镀层表面组织和横截面形貌特征。热浸镀55%A1.Zn镀层在盐雾腐蚀288h时的失重率约为zn镀层的1/2,说明55%Al—zn镀层具有更好的耐蚀性。用电化学阻抗谱方法分析镀层的腐蚀机理,认为55%Al—zn镀层腐蚀前期由扩散控制,后期由于极化电阻的减小,电荷转移增多;而zn镀层腐蚀前期是由于极化电阻减小,电极表面以电荷转移过程为主,后期表现出扩散特征。

英文摘要:

The corrosion behaviors of hot-dip 55% A1-Zn alloy coating and Zn coating steel sheets in salt solution were comparative studied by salt spray corrosion test and immersion corrosion test. The corrosion mechanism of two kinds of coating was analyzed by electrochemical impedance spectroscopy (EIS). The appearance characters of steel sheet surface, where the corrosion products were eliminated, were observed by optical microscope (OM) and scanning electron microscope (SEM). The result of salt spray corrosion indicated that the corrosion resistance of hot-dip 55 % A1-Zn alloy coating was twice as that of hot-dip Zn coating in the same corrosion period of 288 h. During the initial stage of corrosion, the corrosion process of hot-dip 55% A1-Zn alloy coating steel sheet was controlled by the surface diffusion, but during the final stage of corrosion, the controlling step was the charge transfer through the steel sheet surface. The consequence of hot-dip Zn coating was just opposite to hot-dip 55% A1-Zn alloy coating.

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期刊信息
  • 《上海金属》
  • 中国科技核心期刊
  • 主管单位:上海市科学技术协会
  • 主办单位:上海市金属学会
  • 主编:翟启杰
  • 地址:上海市延长路149号15信箱
  • 邮编:200072
  • 邮箱:shmetals@sh163.net
  • 电话:021-56382976 56332810
  • 国际标准刊号:ISSN:1001-7208
  • 国内统一刊号:ISSN:31-1558/TF
  • 邮发代号:4-833
  • 获奖情况:
  • 1991年上海市优秀科技期刊,1996年上海市优秀科技期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国剑桥科学文摘,英国科学文摘数据库,中国中国科技核心期刊,中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:4476