中文摘要：

铜催化的Ullmann类型交叉偶联反应是有机合成中重要的合成方法.与通常有机反应中采用的有机溶剂相比,利用自然界储量丰富、廉价、绿色环保的水作为有机反应介质更符合当前所倡导的＂绿色＂化学和低碳可持续发展的要求.综述了最近几年来水相铜催化的包括C—N,C—O,C—S和C—C等Ullmann类型交叉偶联反应的最新研究进展.

英文摘要：

Copper-catalyzed Ullmann-type coupling reactions have become an important powerful synthetic method in mod- em organic synthesis. Compared with the usually used organic solvent, employing abundant, cheap, environmental-friendly water as reaction media is obviously more fitful for green chemistry and low carbon sustainable development. The recent pro- gress of copper-catalyzed Ullmann-type including C-N, C-O, C-S and C-C coupling reactions by using water as solvent is reviewed.