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烯丙基季磷盐的合成与表征
  • ISSN号：1672-6871
  • 期刊名称：《河南科技大学学报：自然科学版》
  • 时间：0
  • 分类：O623.221[理学—有机化学;理学—化学]
  • 作者机构：[1]河南科技大学高分子科学与纳米技术重点实验室,河南洛阳471003, [2]洛阳师范学院化学化工学院,河南洛阳471022
  • 相关基金：国家自然科学基金项目(20902043);国家科技部科技人员服务企业行动项目(SQ2009GJD0004653)
作者： 刘少祯[1], 李红梅[1,2], 卢敏[1], 姚大虎[1], 张玉清[1]
关键词： 季磷盐, 三苯基磷, 烯丙基溴
中文摘要：

采用两步合成法,用烯丙基溴和三苯基磷为原料,以四氯化碳为溶剂合成中间体溴化烯丙基三苯基磷盐（[ATPH]＋Br-）。经阴离子交换合成新型的季磷盐[ATPH]＋PF6-和[ATPH]＋BF4-。对3种产物的溶解性进行了考察;用IR、1HNMR对目标产物进行了结构表征;用DSC对产物熔点进行了测定。

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期刊信息
  • 《河南科技大学学报：自然科学版》
  • 北大核心期刊（2011版）
  • 主管单位:河南省教育厅
  • 主办单位:河南科技大学
  • 主编：苏娟华
  • 地址：河南省洛阳市开元大道263号
  • 邮编：471023
  • 邮箱：hkdxbz@haust.edu.cn
  • 电话：0379－64231476
  • 国际标准刊号：ISSN：1672-6871
  • 国内统一刊号：ISSN：41-1362/N
  • 邮发代号:36-285
  • 获奖情况:
  • 1999年全国优秀高校自然科学学报及教育部优秀科技...,全国高校自然科学优秀学报,河南省优秀科技期刊
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  • 俄罗斯文摘杂志,美国化学文摘（网络版）,波兰哥白尼索引,德国数学文摘,英国科学文摘数据库,中国中国科技核心期刊,中国北大核心期刊（2008版）,中国北大核心期刊（2011版）,中国北大核心期刊（2014版）
  • 被引量:4775