激活 Eu2+ 的 reddish-orange-emitting Ca3Si2O7 黄磷与 NH4Cl 流动的增加被综合。当黄磷在一篇名字的作文被综合时(Ca0.99Eu0.01 ) 没有流动增加的 3Si2O7,为微红橘子的排放负责的一个 Ca3Si2O7 阶段被识别为绿排放与 a-Ca2SiO4 的一个中间的阶段共存。与 NH4Cl 流动的增加,当因为流动内容是 3 wt% ,纯阶段 Ca3Si2O7 被获得时, a-Ca2SiO4 被压制。通过改变流动的数量,样品的排放颜色能从绿色被调节到微红橘子,相应于到 Ca3Si2O7 的从 a-Ca2SiO4 的阶段转变。通过优化 Eu2+ 的做的集中,为微红橘子的排放的优化光致发光(PL ) 性质能被完成,它在射出二极管(PC-WLEDs ) 的变换黄磷的白光的应用使这种黄磷未来。
Eu2+ -activated reddish-orange-emitting Ca3Si2O7 phosphors were synthesized with the addition of NH4Cl flux.When the phosphors were synthesized in a nominal composition of (Ca0.99Eu0.01)3Si2O7 without flux addition,a Ca3Si2O7 phase responsible for reddish-orange emission was identified to coexist with an intermediate phase of a-Ca2SiO4 for green emission.With the addition of NH4Cl flux,a-Ca2SiO4 was suppressed while the pure phase Ca3Si2O7 was obtained as the flux content was 3 wt%.Through varying the amount of flux,the emission color of samples can be tuned from green to reddish-orange,corresponding to the phase transformation from a-Ca2SiO4 to Ca3Si2O7.Through optimizing the doping concentration of Eu2+ ,the optimized photoluminescence (PL) properties for reddish-orange emission can be achieved,which makes this kind of phosphor prospective in the applications of the phosphor-converted white light emitting diodes (PC-WLEDs).