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Flux-adjusted phase transformation from Ca_2SiO_4 to Ca_3Si_2O_7 with Eu~(2+) activator for white light emitting diodes
  • ISSN号:1673-1905
  • 期刊名称:《光电子快报:英文版》
  • 时间:0
  • 分类:TN312.8[电子电信—物理电子学] TQ424.1[化学工程]
  • 作者机构:[1]School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China, [2]Tianjin Key Laboratory for Photoeleetronic Materials and Devices, Tianjin University of Technology, Tianjin 300384,China, [3]Key Laboratory of Display Materials and Photoelectronic Devices, Ministry of Education, Tianjin University of Technology,Tianjin 300384, China
  • 相关基金:supported by the National Natural Science Foundation of China (Nos.50872091,21076161 and 50802062); the Tianjin Municipal Science/Technology Commission (Nos.10SYSYJC28100 and 2006ZD30); the Tianjin Municipal Higher Education Commission (No.20110304)
中文摘要:

激活 Eu2+ 的 reddish-orange-emitting Ca3Si2O7 黄磷与 NH4Cl 流动的增加被综合。当黄磷在一篇名字的作文被综合时(Ca0.99Eu0.01 ) 没有流动增加的 3Si2O7,为微红橘子的排放负责的一个 Ca3Si2O7 阶段被识别为绿排放与 a-Ca2SiO4 的一个中间的阶段共存。与 NH4Cl 流动的增加,当因为流动内容是 3 wt% ,纯阶段 Ca3Si2O7 被获得时, a-Ca2SiO4 被压制。通过改变流动的数量,样品的排放颜色能从绿色被调节到微红橘子,相应于到 Ca3Si2O7 的从 a-Ca2SiO4 的阶段转变。通过优化 Eu2+ 的做的集中,为微红橘子的排放的优化光致发光(PL ) 性质能被完成,它在射出二极管(PC-WLEDs ) 的变换黄磷的白光的应用使这种黄磷未来。

英文摘要:

Eu2+ -activated reddish-orange-emitting Ca3Si2O7 phosphors were synthesized with the addition of NH4Cl flux.When the phosphors were synthesized in a nominal composition of (Ca0.99Eu0.01)3Si2O7 without flux addition,a Ca3Si2O7 phase responsible for reddish-orange emission was identified to coexist with an intermediate phase of a-Ca2SiO4 for green emission.With the addition of NH4Cl flux,a-Ca2SiO4 was suppressed while the pure phase Ca3Si2O7 was obtained as the flux content was 3 wt%.Through varying the amount of flux,the emission color of samples can be tuned from green to reddish-orange,corresponding to the phase transformation from a-Ca2SiO4 to Ca3Si2O7.Through optimizing the doping concentration of Eu2+ ,the optimized photoluminescence (PL) properties for reddish-orange emission can be achieved,which makes this kind of phosphor prospective in the applications of the phosphor-converted white light emitting diodes (PC-WLEDs).

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期刊信息
  • 《光电子快报:英文版》
  • 主管单位:
  • 主办单位:天津理工大学
  • 主编:巴恩旭
  • 地址:天津市西青区宾水西道391号
  • 邮编:300384
  • 邮箱:Oelett@yahoo.com.cn
  • 电话:022-23679707 23657134
  • 国际标准刊号:ISSN:1673-1905
  • 国内统一刊号:ISSN:12-1370/TN
  • 邮发代号:6-198
  • 获奖情况:
  • 中国期刊方阵“双效”期刊
  • 国内外数据库收录:
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  • 被引量:147