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炼厂含油污水微生物燃料电池的启动及性能研究
  • ISSN号:1003-9015
  • 期刊名称:高校化学工程学报
  • 时间:0
  • 页码:-
  • 分类:X703[环境科学与工程—环境工程]
  • 作者机构:[1]中国石油大学(北京)化工学院,北京102249
  • 相关基金:国家自然科学基金资助项目(20976195)
  • 相关项目:含油污水微生物燃料电池的构建及电池中微生物协同作用和代谢特征研究
作者: 詹亚力|
中文摘要:

以炼油废水为碳源,构建双室填料型微生物燃料电池,考察接种液、外接电阻等电池启动条件,以及电导率、pH值和缓冲溶液强度等溶液性质对电池产电性能的影响。利用微生物燃料处理炼油废水,COD去除率(52±4)%,含油量去除率(81.8±3)%;利用废水中存在的原生菌即可启动电池,但启动期长,外加接种液可快速启动电池;启动时外接电阻的大小对电池稳定运行后的输出功率有明显影响,对电池内阻影响相对较小,当启动外接电阻为2 000Ω,电池输出功率最大,为288 mW/m3;随阳极溶液电导率电池增大,电池内阻降低,输出功率升高;pH值变化对电池阳极电势影响较大,进而影响电池输出,当溶液pH为9时,电池输出电压最大(388 mV),pH过高或过低均不利于电池产电;随着缓冲强度的增大,电池输出电压增大,且PBS缓冲强度的增大可从电导率增大和改善质子传递条件两方面提高电池的输出功率。

英文摘要:

A two-chambered packing type microbial fuel cell (MFC) with refinery wastewater as its fuel was constructed to study the influence of starting conditions which included inoculum, external resistance, and solution properties of conductivity, pH and PBS strength on electricity generation of MFC. After being treated by MFC, COD removal rate of refinery wastewater was (52 ±4) % , and that for oil was (81. 8± 3 ) %. Microorgan- isms existed in initial wastewater could start up MFC, but the start-up period was long, and inoculums were nee- ded to start up MFC quickly. The influence of external resistance used at start-up period on power density was obvious, while its influence on internal resistance of MFC was relatively little, and power density of MFC was 288 mW/m3 , highest of all, when start-up external resistance was 2 000 Ω. Power density increased and internal resistance decreased following with the increase of anolyte conductivity. The optimal performance of MFC was a- chieved when pH value was 9 (388 mV) , and performance of MFC was worse at both lower and higher pH val- ue. Power density increased with the increase of buffer intensity.

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期刊信息
  • 《高校化学工程学报》
  • 北大核心期刊(2011版)
  • 主管单位:国家教育部
  • 主办单位:浙江大学
  • 主编:陈纪忠
  • 地址:杭州浙大路38号浙江大学玉泉校区化工系
  • 邮编:310027
  • 邮箱:gxhgxb@zju.edu.cn
  • 电话:0571-87951235
  • 国际标准刊号:ISSN:1003-9015
  • 国内统一刊号:ISSN:33-1141/TQ
  • 邮发代号:
  • 获奖情况:
  • 2000年获浙江省科技期刊编辑学会颁发的“1999-200...,中国期刊方阵“双效”期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:14205