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Substitute of Expensive Pt with Improved Electrocatalytic Performance and Higher Resistance to CO Poisoning for Methanol Oxidation: the Case of Synergistic Pt-Co3O4 Nanocomposite
  • ISSN号:1006-3536
  • 期刊名称:《化工新型材料》
  • 时间:0
  • 分类:O643.36[理学—物理化学;理学—化学] TM911.4[电气工程—电力电子与电力传动]
  • 作者机构:Key Laboratory of Micro-Nano Materials for Energy Storage and Conversion of Henan Province, Institute of Surface Micro and Nano Materials, Xuchang University, Chengdu Green Energy and Green Manufacturing R&D Center
  • 相关基金:supported by National Natural Science Foundation of China (Grant No. 21273192, 91023010, 61204009, 21303153);Innovation Scientists and Technicians Troop Construction Projects of Henan Province (Grant No. 104100510001);the Program for Science & Technology Innovation Talents in Universities of Henan Province (2008 HASTIT016);Henan Province Science and Technology Key Project (Grant No. 082102230036 and 122102210479)
中文摘要:

In this paper, Pt-Co3O4 nanocomposite was synthesized by a sol gel process combined with electrodeposition method. Its electrocatalytic activity towards methanol oxidation was investigated at room temperature using cyclic voltammetry(CV), electrochemical impedance spectroscopy(EIS) and current density time curve. It is found that the resultant Pt-Co3O4 catalysts with minute amount of Pt exhibite attractive electrocatalytic activity for methanol oxidation reaction(MOR) but with a high resistance CO poisoning due to the synergistic effects from Pt and Co3O4. Together with the low manufacturing cost of Co3O4, the reported nanostructured Pt-Co3O4 catalyst is expected to be a promising electrode material for direct methanol fuel cells(DMFC).

英文摘要:

In this paper, Pt-Co3O4 nanocomposite was synthesized by a sol-gel process combined with electrodeposition method. Its electrocatalytic activity towards methanol oxidation was investigated at room temperature using cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and current density-time curve. It is found that the resultant Pt-Co3O4 catalysts with minute amount of Pt exhibite at tractive electrocatalytic activity for methanol oxidation reaction (MOR) but with a high resistance CO poisoning due to the synergistic effects from Pt and Co3O4. Together with the low manufacturing cost of Co3O4, the reported nanostructured Pt-Co3O4 catalyst is expected to be a promising electrode material for direct methanol fuel cells (DMFC).

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期刊信息
  • 《化工新型材料》
  • 北大核心期刊(2011版)
  • 主管单位:中国石油和化学工业联合会
  • 主办单位:中国化工信息中心
  • 主编:李海娜
  • 地址:北京安定门外小关街53号
  • 邮编:100029
  • 邮箱:hgxx@cncic.cn
  • 电话:010-64437113
  • 国际标准刊号:ISSN:1006-3536
  • 国内统一刊号:ISSN:11-2357/TQ
  • 邮发代号:82-816
  • 获奖情况:
  • 国内外数据库收录:
  • 美国化学文摘(网络版),中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:20192