由于分子磁性材料具有密度小、易裁剪和易复合等特点,其在信息存储、光磁开关和医疗诊断等方面具有潜在重要的应用价值,受到了广泛的关注,TCNQ金属配合物作为分子磁性材料的重要组成部分受到了化学工作者的青睐。TCNQ金属配合物的合成结构及性能研究取得了丰硕的成果。课题组近年来在该领域开展了一些工作,对该领域的研究工作有一些体会。综述了T'CNQ过渡金属和稀土配合物的结构和性能方面的研究进展。
The design of ligan&moderated metal complexes is important because of their unique physico- chemical properties and potential applications as functional materials. Especially, the magnetic properties of metal complexes have attracted much attention. Since trivalent lanthanide ions generally have large anisotropic magnetic moments arising from a large number of spins and strong spin-orbit couplings, they have been extensively employed to prepare molecular-based magnets with paramagnetic transition metal ions or organic radicals. The synthesis, structure and properties of TCNQ metal complexes have made great progress. In recent years, we carry out some research in this field. To provide some reference for the researchers, the synthesis and magnetism of TCNQ metal complexes are summarized in this paper.