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热CVD法制备的碳纳米管线阵列的场发射特性
  • 期刊名称:液晶与显示,24(1),43-47(2009)
  • 时间:0
  • 分类:TN912.1[电子电信—通信与信息系统;电子电信—信息与通信工程] TB383[一般工业技术—材料科学与工程]
  • 作者机构:[1]中国科学院长春光学精密机械与物理研究所,吉林长春130033, [2]中国科学院研究生院,北京100039
  • 相关基金:国家自然科学基金资助项目(No.60571004,No.60877007);国家重点基础研究发展规划(“973”计划)项目(No.2003CB314701)
  • 相关项目:碳纳米管场发射电学接触及物理研究
中文摘要:

采用半导体光刻技术在硅衬底上获得图形化掩膜,然后用热化学气相淀积(T-CVD)的方法制备了图形化的碳纳米管线阵列,用扫描电镜和拉曼光谱仪对碳纳米管进行了表征。研究了图形化碳纳米管线阵列的场发射特性,并与无图形化处理的碳纳米管薄膜样品的场发射特性进行了比较。当发射电流密度达到10gA/cm^2时,无图形化处理的碳纳米管薄膜、10μm碳纳米管线阵列以及2μm碳纳米管线阵列样品的开启电场分别为3V/μm、2.1V/μm和1.7V/μm;而当电场强度达3.67 V/μm时,相应的电流密度分别为2.57mA/cm^2、4.65mA/cm^2和7.87mA/cm^.实验结果表明,图形化处理后的碳纳米管作为场发射体,其场发射特性得到了明显的改善。对改善的原因进行了分析和讨论。

英文摘要:

Using standard photolithography, patterned carbon nanotube line arrays were fabricated con substrates by thermal chemical vapor deposition. Scanning electron microscopy and Raman spec- troscopy were used to characterize the structure of the carbon nanotubes. The carbon nanotubes were very uniform and about 50 nm in diameter and 2 μm in length. The Raman spectrum showed that the carbon nanotubes were multi-walled carbon nanotubes. Field emission characteristics of the samples were characterized. It was found that the non-patterned carbon nanotube films, 10 μm and 2 μm size carbon nanotube line arrays field emission characteristics were gradually improved with turn-on field of 3 V/μm,2.1 V/μm, 1.7 V/μm and emission current density at applied electric field 3.67 V/m were 2.57 mA/cm^2 ,4. 65 mA/cm^2 , 7. 87 mA/cm^2 , respectively. The reasons may attribute to the fieldscreening effect and edge effect by analyzing the experimental results.

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