通过水热合成方法合成了超分子化合物[(4,4′-bipy)4H5][BW12O40].2H2O,并采用红外光谱、元素分析、单晶X射线衍射对其进行了表征.结果表明:该晶体属于单斜晶系,C2/C空间群;晶胞参数a=2.179 5(5)nm,b=1.393 9(5)nm,c=2.128 9(5)nm,α=90°,β=104.166(5)°,γ=90°,V=6.271(3)nm3,Z=4,R1=0.072 5,wR2=0.294 3.
A super molecular complex [(4,4′-bipy)4H5][BW12O40]·2H2O was synthesized by IR,elemental analyses and single-crystal X-ray diffraction.The crystal data for this compound are the following:monoclinic,space group C2/C,a=2.179 5(5) nm,b=1.393 9(5) nm,c=2.128 9(5) nm,α=90°,β=104.166(5)°,γ=90°,V=6.271(3) nm3,Z=4,R1=0.072 5,wR2=0.294 3.