位置:成果数据库 > 期刊 > 期刊详情页
干胶法合成分子筛
  • ISSN号:1005-281X
  • 期刊名称:Progress in Chemistry
  • 时间:2012
  • 页码:253-261
  • 分类:O643.13[理学—物理化学;理学—化学] TB383[一般工业技术—材料科学与工程]
  • 作者机构:[1]华东师范大学化学系上海市绿色化学与化工过程绿色化重点实验室,上海200062, [2]曲阜师范大学化学与化工学院,曲阜273165
  • 相关基金:国家自然科学基金项目(No.20890124,21003083)和中国博士后科学基金项目(No.201004700766)资助
  • 相关项目:干凝胶法纳米沸石制备及原位组装
中文摘要:

相对于传统的水热合成法,干胶法(drygelconversion,DGC)合成分子筛具有产量高、废液量少等优势。本文综述了近十年来DGC合成分子筛的研究进展。以水为线索,总结了外加水和固有水(指原料干胶所含的水)在DGC中对分子筛的生长、晶相的转换与物化性质的影响,论述了在DGC条件下分子筛的生长过程和晶化机理,介绍了DGC在介孔一微孔复合分子筛、分子筛膜、单块材料等新型分子筛材料合成中的一些实例。

英文摘要:

Compared with traditional hydrothermal synthesis (HTS), dry gel conversion (DGC) synthesis of zeolites has the advantages of high yield, less waste, less usage of templates,etc. Firstly, this review summarized the developments in last decade and pivoted on the role of water. In typical DGC synthesis, the gel powder keeps intact with the liquid including liquid water. However, water could also be the vapor or those adsorbed/absorbed in gel powders. Therefore, both the water added and those included in gel powder may affect the nucleation, and growth of zeolite, phase selectivity and transformation, and the properties of obtained zeolite. It is believed that water has been the prerequisite for the transformation of zeolite from initial gel. And the required amount of water differs by structural properties of zeolite. Apart from water, other factors have been seen as contributing roles as well in the synthesis condition. Secondly, the difference between HTS and DGC is discussed. Thirdly, this review provided some insights into the formation mechanism of zeolite in DGC process, where nanoparticles and semi- crystalline intermediates play the role. Finally, this review illustrated the applications of DGC in the synthesis of hierarchical zeolite, zeolite film, zeolite monolith and others. Some advices about DGC used in the synthesis of these relatively new materials are concluded.

同期刊论文项目
期刊论文 7 会议论文 2
同项目期刊论文
期刊信息
  • 《化学进展》
  • 北大核心期刊(2011版)
  • 主管单位:中国科学院
  • 主办单位:中国科学院基础研究局 化学部 文献情报中心
  • 主编:
  • 地址:北京中关村四环西路33号
  • 邮编:100080
  • 邮箱:scinfo@mail.las.ac.cn
  • 电话:010-82627757
  • 国际标准刊号:ISSN:1005-281X
  • 国内统一刊号:ISSN:11-3383/O6
  • 邮发代号:82-645
  • 获奖情况:
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国科学引文索引(扩展库),日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:21655