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Effect of salt solutions on chain structure of partially hydrolyzed polyacrylamide
  • 时间:0
  • 分类:TQ323.7[化学工程—合成树脂塑料工业]
  • 作者机构:[1]College of Chemistry and MacDiarmid Laboratory,Jilin University
  • 相关基金:Project(50673033) supported by the National Natural Science Foundation of China
  • 相关项目:自模板法SiO2/PPV纳米杂化微球的制备及作为生物标记材料的应用
中文摘要:

The effect of salt solutions(NaCl,Na2SO4 and CaCl2) on the conformational properties of partially hydrolyzed polyacrylamide(HPAM) was investigated by using static laser light scattering(SLLS).The special interaction between CaCl2 solution and HPAM was also researched.Experimental results show that the chain structure of HPAM is interrelated with the charge density,the kind and the concentration of salt solutions.The mean-square radius of gyration(Rz) and the second virial coefficient(A2) of HPAM decrease with increasing concentration of salt solutions,and the salt effect tends towards the maximum when the concentration of salt solution is increased to some amount.

英文摘要:

The effect of salt solutions (NaCl, Na2SO4 and CaCl2) on the conformational properties of partially hydrolyzed polyacrylamide (HPAM) was investigated by using static laser light scattering (SLLS). The special interaction between CaCl2 solution and HPAM was also researched. Experimental results show that the chain structure of HPAM is interrelated with the charge density, the kind and the concentration of salt solutions. The mean-square radius of gyration (R z) and the second virial coefficient (A 2) of HPAM decrease with increasing concentration of salt solutions, and the salt effect tends towards the maximum when the concentration of salt solution is increased to some amount.

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