氮氧自由基因其结构优势已成为有机磁体的重要构件。从纯氮氧自由基类有机磁体和含金属的氮氧自由基类有机磁体两方面综述了氮氧自由基类有机磁体的结构、种类及发展历史。分析指出氮氧自由基类有机磁体目前存在的主要问题是转换温度Tc较低及磁构关系不明确,但由于其具有诸多的优越性能而将得到大力研发。
Owing to its structural advantage, the free radical of nitroxide has been an important component for organic magnets. In view of pure and metal-contained organic magnets, this paper reviews the species, structures and development history of organic magnets containing free radical of nitroxide. These analyses indicate that the primary problems at present are lower Curie temperature and the unclear relationship between the magnetism and the structure, but duo to its distinguishing performance, organic magnet will be well studied and developed.