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Al(OH)3和α-SiO2对聚磷酸铵热分解过程的影响
  • ISSN号:0454-5648
  • 期刊名称:《硅酸盐学报》
  • 时间:0
  • 分类:TQ314.248[化学工程—高聚物工业] P578.959[天文地球—矿物学;天文地球—地质学]
  • 作者机构:[1]. State Key Laboratory of Advanced Technology for Materials-Synthesis and Processing, Wuhan University of Technology,Wuhan 430070, China, [2]School of Chemical and Environment Engineering, Hubei University for Nationalities, Enshi 445000, China
  • 相关基金:Funded by the National Natural Science Foundation of China(No.51472188)
中文摘要:

分别地,与白云母(应用软件 / 白云母) 混合的铵 polyphosphate (应用软件) 的相互作用机制和阶段进化被 TG, XRD 和 SEM 在加热期间学习。温度什么时候不比 300 高 ?  ????? ㄠ‰??

英文摘要:

The interaction mechanism and phase evolution of ammonium polyphosphate(APP)mixed with muscovite(APP/muscovite)were studied by TG,XRD and SEM,respectively,during heating.When the temperature is not higher than 300 ℃,muscovite has no effect on the thermaldecomposition of APP,and the initialdecomposition temperature of APP/muscovite at 283 ℃ is basically the same as the APP at 295 ℃,and the main thermaldecomposition products are polyphosphoric acid and NH_4H_2PO_4 at 300 ℃.The polyphosphoric acid,the decomposition products of APP,can enable K and Siout of muscovite and interact with muscovite chemically to generate Al_2O_3·2SiO_2,α-SiO_2 and phosphates(AlPO_4 and K_5P_3O_(10))compounds during 400 ℃-800 ℃,which own obvious adhesive phenomenon and porous structure with the apparent porosity of 58.4%.Further reactions between phosphates other than reactions among Al_2O_3·2SiO_2 and α-SiO_2 can generate KAlP_2O_7 at 1 000 ℃ and the density of residualproduct is improved by low melting point phosphate filling pore to form relatively dense structure and decrease the apparent porosity to 44.4%.The flame resistant and self-supported ceramic materials are expected to enhance the fire-retarding synergistic effect between APP and muscovite.

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期刊信息
  • 《硅酸盐学报》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:中国硅酸盐学会
  • 主编:南策文
  • 地址:北京海淀区三里河路11号
  • 邮编:100831
  • 邮箱:jccsoc@sina.com
  • 电话:010-57811253 57811254
  • 国际标准刊号:ISSN:0454-5648
  • 国内统一刊号:ISSN:11-2310/TQ
  • 邮发代号:2-695
  • 获奖情况:
  • EI Compendex、CA、SA、PI收录期刊,全国核心期刊,中国期刊方阵“双效”期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:27713