报道了W/O柠檬酸配合物的合成及结构,并用元素分析、红外光谱、紫外.可见光谱、光电子能谱、核磁、热重、差热分析等手段进行了表征,而且还用EHMO方法研究了配合物的电子结构,解释了该类配合物的羧基红外振动峰是一宽峰且有劈裂的特点.
W/O complex with a citrate ligand has been prepared and characterized by the means of dement analysis, IR, UV-vis, NMR and TG-DTA. Its electronic structure is discussed by using EHMO method. The fact that IR vibrating peaks of the carboxyl group have made a wide and split peak is explained in this paper.