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Synthesis and Characterization of Sphere-like Pt Nanoparticles Supported on DWCNT/WO3 Nanorods with Electrocatalytic Activity
  • ISSN号:1005-0302
  • 期刊名称:《材料科学技术学报:英文版》
  • 时间:0
  • 分类:TQ153.2[化学工程—电化学工业] TB383[一般工业技术—材料科学与工程]
  • 作者机构:[1]State Key Laboratory Breeding Base for Green Chemistry Synthesis Technology, International Science & Technology Cooperation Base of Energy Materials and Application, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310032, China, [2]Engineering Research Center of High-efficiency Development and Application Technology of Tungsten Resources (Ministry of Education), School of Materials Science and Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China
  • 相关基金:financially supported by the Science and Technology Major Project in International Cooperation of Zhejiang Province (No. 2008C14040);the Key Project of Natural Science Foundation of Zhejiang Province (No. Z4100790);the International Science and Technology Cooperation Program of China (No. 2010DFB63680);the Department of Educational, Science & Technology, and Human Resources & Social Security of Jiangxi Province (Nos. GJJ12366, 20122BAB216013, 20121BBE50027, [2012]195);the National Natural Science Foundation of China (Nos. 51202095 and 51264010)
中文摘要:

Tungsten oxide(WO3) nanorods, which were used to load platinum(Pt) nanoparticles, were investigated. H2WO4 nanorods with diameters from 10 to 50 nm were obtained when tungsten precursor was added into homogenous double-walled carbon nanotubes(DWCNT) and ethylene glycol(EG) solution.Nanosized rod-like WO3 were achieved after calcination of the DWCNT/H2WO4 composite. Sphere-like Pt nanoparticles were loaded on the surface of the nanorods by EG in-situ reduction. Pt particles were isolated by DWCNT/WO3 nanorods and secondary accumulation could be prevented when Pt particles appeared in the DWCNT/WO3 nanorod/EG dispersion solution. Therefore, Pt nanoparticles with mean diameters of 2–6 nm could be obtained. Pt-deposited on DWCNT/WO3 nanorods exhibited high electrochemical activity, which could facilitate the low-cost mass production of Pt catalyst.

英文摘要:

Tungsten oxide (WO3) nanorods, which were used to load platinum (Pt) nanoparticles, were investi- gated. H2WO4 nanorods with diameters from 10 to 50 nm were obtained when tungsten precursor was added into homogenous double-walled carbon nanotubes (DWCNT) and ethylene glycol (EG) solution. Nanosized rod-like WO3 were achieved after calcination of the DWCNT/H2W04 composite. Sphere-like Pt nanoparticles were loaded on the surface of the nanorods by EG in-situ reduction. Pt particles were isolated by DWCNT/WO3 nanorods and secondary accumulation could be prevented when Pt particles appeared in the DWCNT/WO3 nanorod/EG dispersion solution. Therefore, Pt nanoparticles with mean di- ameters of 2-6 nm could be obtained. Pt-deposited on DWCNT/WO3 nanorods exhibited high electrochemical activity, which could facilitate the low-cost mass production of Pt catalyst.

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期刊信息
  • 《材料科学技术学报:英文版》
  • 中国科技核心期刊
  • 主管单位:中国科协
  • 主办单位:中国金属学会
  • 主编:
  • 地址:中国沈阳文化路72号
  • 邮编:110016
  • 邮箱:
  • 电话:024-83978208
  • 国际标准刊号:ISSN:1005-0302
  • 国内统一刊号:ISSN:21-1315/TG
  • 邮发代号:
  • 获奖情况:
  • 国家“双百”期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,美国科学引文索引(扩展库),日本日本科学技术振兴机构数据库,中国中国科技核心期刊
  • 被引量:474