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化学镀法制备Pt/Au—PAN催化电极及其催化氧化甲醇性能研究
  • ISSN号:0253-2395
  • 期刊名称:《山西大学学报:自然科学版》
  • 时间:0
  • 分类:O613.71[理学—无机化学;理学—化学] TM53[电气工程—电器]
  • 作者机构:Institute of Molecular Science, Key Laboratory of Shanxi Province for Energy Conversion and Storage Materials, Shanxi University, Taiyuan, Shanxi 030006, China
  • 相关基金:Acknowledgement The authors thank the National Natural Science Foundation of China (21574076, 21274082, 21501113, 61504076 and 21407100) and Science Foundation of Shanxi Province (2014011016-1), the Program for New Century Excellent Talents in University (NCET-10- 0926) of China and the Program for the Top Young and Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi (02035290 1014).
中文摘要:

一条环境地友好的途径被介绍综合 sulfonated 由使用 L 维生素酸(L-AA ) 和 sulfanilic 酸的芳基重氮基盐减少了 graphene 氧化物(S-rGO ) 。准备条件被优化了以便获得孤立,传导性的 S-rGO,和产品被紫外可见的光谱学描绘了, Fourier 转变了红外线的光谱学,拉曼, X 光检查光电子光谱学和 X 光检查粉末衍射和电气化学的方法。结果证明 S-rGO 表拥有优秀水溶性和高电的电导率,它暗示包含氧的功能的组被搬迁了并且结合 sp 2 网络被恢复了。而且,电气化学的大小表明 S-rGO 的电容的表演与 graphene 氧化物相比被改进了(去) 并且减少的 graphene 氧化物(rGO,由 L-AA 减少了) 。最佳 S-rGO 展出 205 F·g −1 和好骑车稳定性的一个特定的电容(3.9% 在 10000 以后减少骑车) ,它比对 graphene 氧化物的那些好(109 F·g −1 并且减少 6.6% 在 10000 个周期以后) 并且 rGO (139 F·g −1 并且减少 11.3% 在 10000 骑车以后) 。这条途径证明一条新线路改进 rGO 的电容的性质。

英文摘要:

An environmentally friendly approach is presented to synthesize sulfonated reduced graphene oxide (S-rGO) by using L-ascorbic acid (L-AA) and aryl diazonium salt of sulfanilic acid. The preparation conditions have been optimized in order to obtain isolated and conductive S-rGO, and the products have been characterized by Ultraviolet-Visible spectroscopy, Fourier transformed infrared spectroscopy, Raman, X-ray photoelectron spectroscopy and X-ray powder diffraction and electrochemical methods. The results show that the S-rGO sheets possess excellent water-solubility and high electrical conductivity, which implies that the oxygen-containing functional groups have been removed and conjugated sp2 network has been restored. What's more, the electrochemical measurements reveal that the capacitive performance of the S-rGO has been improved compared with the graphene oxide (GO) and the reduced graphene oxide (rGO, reduced by L-AA). The optimum S-rGO exhibits a specific capacitance of 205 F·g^-1 and good cycling stability (3.9% decreasing after 10000 cycles), which are better than those for graphene oxide (109 F·g^-1 and decreasing 6.6% after 10000 cycles) and rGO (139 F·g^-1 and decreasing ll.3% after 10000 cycling). This approach proves a new route to improve the capacitive properties of rGO.

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期刊信息
  • 《山西大学学报:自然科学版》
  • 北大核心期刊(2011版)
  • 主管单位:山西省教育厅
  • 主办单位:山西大学
  • 主编:杨斌盛
  • 地址:太原市坞城路92号
  • 邮编:030006
  • 邮箱:xbbjb@sxu.edu.cn
  • 电话:0351-7010455
  • 国际标准刊号:ISSN:0253-2395
  • 国内统一刊号:ISSN:14-1105/N
  • 邮发代号:22-42
  • 获奖情况:
  • 边疆七年获山西省一级期刊荣誉(1993-1999)
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),英国动物学记录,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:5651