位置：成果数据库 > 期刊 > 期刊详情页
影响总氮准确定量的光谱检测因素
  • ISSN号：1002-6002
  • 期刊名称：《中国环境监测》
  • 时间：0
  • 分类：X832[环境科学与工程—环境工程]
  • 作者机构：[1]珠江水利委员会珠江水利科学研究院,广东广州510611, [2]华南理工大学制浆造纸工程国家重点实验室,广东广州510640
  • 相关基金：国家自然科学基金项目（21037001,21076091）; 水利部公益性项目行业科研专项“珠江河流生物指标水质评价体系”; 珠江水利科学研究院开放基金的资助
作者： 蒋然[1], 柴欣生[2], 张翠[2]
关键词： 总氮, 紫外分光光度法, 三波长, Total nitrogen, UV spectroscopy, Tri-Wavelength
中文摘要：

对现行的双波长紫外分光光度法在测定水体总氮中由光学检测本身所产生的影响因素进行了探讨,提出了一种基于三波长的光谱检测总氮量的方法。结果表明,由于仪器信号波动或光散射引起的光谱检测基线上移所造成的误差可以用在NO3-没有吸收的340 nm处的吸光度加以判断,从而用三波长的方法扣除由于光谱基线上移对220 nm和275 nm处吸光度检测的干扰。对2个水样进行同样的光谱检测,以不同的计算公式所得的数据比较可以看出,三波长法明显优于双波长法。三波长法检测重现性相对偏差小于0.2%,其总氮含量的结果要比双波长法高7%～16%。这也解决了人们对总氮含量测定结果总是偏低的困惑。

英文摘要：

The paper reports a tri-wavelength spectroscopic method for accurate determination of total nitrogen（TN） in aqueous samples.It is based on the standard dual-wavelength method currently used for TN testing,however a new wavelength,340 nm is introduced.By taking the absorption at 340 nm as a reference,the spectral errors caused by the light scattering or the instability of the spectrophotometer during the sample measurement can be corrected.The results showed that the tri-wavelength method dramatically improves a measurement precision（RSD 0.2%）.The calculated results for TN content from the tri-wavelength method for two given samples are 7% and 16%,respectively,greater than those obtained by the dual-wavelength method,which also solves a long puzzle why TN content is under-estimated in the two-wavelength method.The present method is simple,reliable and accurate.

同期刊论文项目
煤化工过程废水中典型污染物生成机制与控制原理
期刊论文 161
蒽醌在碱法制浆过程中传质机理的研究
期刊论文 47
同项目期刊论文
Rapid Determination of Benzene Derivatives in Water Samples by Trace Volume Solvent DLLME prior to G
Distribution and health-risk of polycyclic aromatic hydrocarbons in soils at a coking plant
<span style="font-family:宋体;font-size:10.5pt;">电驱动下的环境污染物厌氧生物转化</span><span
聚羟基丁酸酯(PHB)对水中微量多环芳烃的仿生吸附
底隙十字挡板对四边形流化床流体力学性能优化数值模拟
Study on preparation and properties of PVA-SA-PHB-AC composite carrier for microorganism immobilizat
化学沉淀结合Fenton法预处理脱硫废液的原理与效果分析
Partial oxidative gasification of phenol for hydrogen in supercritical water
Pyrene degradation by Pseudomonas sp and Burkholderia sp enriched from coking wastewater sludge
One-step electrosynthesis of polypyrrole/graphene oxide composites for microbial fuel cell applicati
产酸克雷伯氏菌Klebsiella oxytoca对硝基苯及4-氯硝基苯的降解
焦化废水生物处理过程多环芳烃的生物降解
阴极硝化耦合阳极反硝化实现微生物燃料电池技术脱氮
An Analysis of the Toxicity of Nitroaromatic Compounds to Tetrahymena pyriformis Using the Quantitat
The behaviors and fate of polycyclic aromatic hydrocarbons (PAHs) in a coking wastewater treatment p
The occurrence and fate of phenolic compounds in a coking wastewater treatment plant
Ion-exchange membrane bioelectrochemical reactor for removal of nitrate in the biological effluent f
Fiber-assisted emulsification microextraction coupled with gas chromatography–mass spectrometry for
Efficient adsorption of phenanthrene by simply synthesized hydrophobic MCM-41 molecular sieves
Preparation of trimethylchlorosilane-modified acid vermiculites for removing diethyl phthalate from
<span style="font-family:宋体;font-size:10.5pt;">一种检测低浓度化学需氧量的双波长光谱方法</span>
Energetic Analysis of Gasification of Biomass by Partial Oxidation in Supercritical Water
卤代有机污染物的光化学降解
超亲水性介孔SiO_2防雾薄膜的制备及条件优化
活性炭纤维吸附处理模拟焦化废水尾水
Estrogenic activity and identification of potential xenoestrogens in a coking wastewater treatment p
疏水性MCM-41介孔分子筛对水溶液中双酚A的吸附研究
超亲水性介孔SiO2/Bi2O3/TiO2分层薄膜的制备及其自洁净性能研究
脱氮与除碳协同的电化学生物流化床构建与运行工况分析
<strong>酸化蛭石的表面有机修饰及其对疏水性微污染物的吸附</strong>
Anode-biofilm electron transfer behavior and wastewater treatment under different operational modes
In vivo tracing uptake and elimination of organic pesticides in fish muscle
Anode modification with capacitive materials for a microbial fuel cell: an increase in transient pow
Photocatalytic oxidation of NOx over TiO2/HZSM-5 catalysts in the presence of water vapor: Effect of
Preparation of superhydrophilic mesoporous SiO2 thin films
One-step fabrication of membraneless microbial fuel cell cathode by electropolymerization of polypyr
Adsorption dynamics of trichlorofluoromethane in activated carbon fiber beds
A new method for the determination of biological oxygen demand in domestic wastewater by headspace g
焦化废水中有机物的识别、污染特性及其在废水处理过程中的降解
酚类化合物在焦化废水处理过程中的降解与转移
焦化废水尾水中被O<sub>3</sub>/UV氧化的组分辨析及关键组分动力学
A New Developed Airlift Reactor Integrated Settling Process and Its Application for Simultaneous Nit
Thiocyanate Oxidation by Coculture from a Coke Wastewater Treatment Plant
H_2O_2/UV流化床氧化焦化废水尾水中惰性成分的可行性考察
酵母废水处理技术分析及生物流化床耦合工艺的应用实践
缩聚-Fenton-A/O生物流化床组合工艺处理酚醛废水的工程案例分析
<span style="font-family:宋体;font-size:10.5pt;">影响总氮准确定量的光谱检测因素</span>
典型POPs的生物降解修复技术研究与发展
持久性有机污染物的水污染控制:吸附富集、生物降解与过程分析
焦化废水中溶解性有机物组分的特征分析
诺氟沙星水溶液的湿式氧化分解及其产物的生成途径
有机粘土疏水性吸附过程的分子模拟:烷基碳原子数和有机物logK_(ow)的影响
基于CFD的内构件强化内循环流化床流场结构分析
Gasification of alga Nannochloropsis sp in supercritical water
固定化Lysinibacillus cresolivorans的PVA-SA-PHB-AC复合载体制备及间甲酚的降解
焦化废水处理过程外排污泥中重金属形态特征及其潜在环境风险
{001}面TiO_2光催化降解罗丹明B的研究
O_3/UV深度处理焦化废水的条件控制及其效能评估
微波消解-石墨炉原子吸收法测定沉积物中重金属的全量及形态
可见光响应Pt掺杂纳米TiO2的光催化氧化NOx性能
Isolation and Identification of Achromobacter sp DN-06 and Evaluation of Its Pyridine Degradation Ki
Hydrothermal Gasification of Nannochloropsis sp with Ru/C
Rapid determination of anilines in water samples by dispersive liquid-liquid microextraction based o
Kinetic model for supercritical water gasification of algae
超亲水性含钛介孔SiO<sub>2</sub>薄膜的制备及其自洁净性能研究
Heterotrophic nitrification and aerobic denitrification bacterium isolated from anaerobic/anoxic/oxi
Rapid Determination of Quinoline and 2-Hydroxyquinoline in Quinoline Biodegradation Process by Tr-Wa
Stainless steel mesh coated with MnO2/carbon nanotube and polymethylphenyl siloxane as low-cost and
短波紫外对铜绿微囊藻的灭活与微囊藻毒素的降解
废水处理生物出水中COD构成的解析——以焦化废水为例
一种检测低浓度化学需氧量的双波长光谱方法
可燃吸附剂从焦化废水中分离潜热实现低能耗工艺的实验研究——以活性炭为例
基于结构参数响应的内循环流化床流体特性优化数值模拟
养殖污水生物处理的新型流态化技术原理及其应用案例
不同煅烧温度制备的Mn、N掺杂TiO<sub>2</sub>光催化性能研究
新型流化床内流体重构的流体力学特性变化及其数值模拟
硝基芳烃对梨形四膜虫毒性的定量构效关系解析
Ruthenium oxide-coated carbon felt electrode: A highly active anode for microbial fuel cell applicat
焦化废水中硫氰化物的快速检测方法
Effect of the local structures of V-oxides in MCM-41 on the photocatalytic properties for the partia
煤化工中焦化废水的污染、控制原理与技术应用
焦化废水缓冲体系的存在证明与集水调节池中水质结构调控
Competitive microbial reduction of perchlorate and nitrate with a cathode directly serving as the el
Degradation of m-cresol via the ortho cleavage pathway by Citrobacter farmeri SC01
O/H/O生物工艺中焦化废水含氮化合物的识别与转化
焦化废水尾水O3氧化消除消毒副产物生成潜能的影响分析
Conductive polymer-mediated Cr(VI) reduction in a dual-chamber microbial fuel cell under neutral con
Microbial fuel cell as a biocapacitor by using pseudo-capacitive anode materials
<span style="font-family:宋体;font-size:10.5pt;">焦化废水生物处理</span><span style=&
焦化废水生物处理A/O/H/O工艺中氰化物的去除特性
疏水性分子筛对焦化废水生物处理尾水的吸附过程解析
Treatment of food processing wastewater in a full-scale jet biogas internal loop anaerobic fluidized
印染废水处理工程的新型生物流化床组合工艺技术分析
<span style="font-family:宋体;font-size:10.5pt;">锐钛矿</span><span style="
黏胶基活性碳纤维吸附吡啶
水中持久性有机氯化物的污染形成与控制策略
Energetic Analysis of Gasification of Biomass by Partial Oxidation in Supercritical Water
一种快速测定桉木碱法制浆黑液中残余有效碱的方法
一种快速测定蒽醌含量的可见光谱方法
描述桉木硫酸盐浆氧脱木素过程动力学的新模型
速生桉木硫酸盐浆氧脱木素过程中甲醇生成的动力学模型
硫酸盐法制浆中液比对后续洗浆耗水量的影响
球磨法制备超微细蒽醌及其表征
液比对速生桉木硫酸盐制浆效果的影响
一种检测低浓度化学需氧量的双波长光谱方法
南方松硫酸盐浆氧脱木素过程中甲醇生成的动力学模型
Determination of Degree of Substitution in Succinic Anhydride Modified Cellulose by Headspace Gas Ch
An improved Sample Preparation Method for Monomer Conversion Measurement Using Headspace Gas Chromat
Pathways and Kinetics of Partial Oxidation of Phenol in Supercritical Water
BCTMP 纸页中甲醇向空气释放经验模型的建立
酸处理对桉木浆过氧化氢漂白废液成分影响的研究
样品制备条件对卫生纸菌落总数检测影响的研究
一种用于测定纸浆中过渡金属含量的样品预处理方法
一种检测木质纤维素原料中铁含量的三波长可见光谱法
A Full Evaporation Headspace Gas Chromatographic Method for Determination of Monomer Conversion in C
A novel method for the determination of adsorption partition coefficients of minor gases in a shale
Determination of Epichlorohydrin and 1, 3-Dichloro-2-Propanol in Synthesis of Cationic Etherifying R
A Novel Method for Determination of Ethoxyl Content in Ethyl Cellulose by Headspace Gas Chromatograp
Oxalate Release and Formation during Alkaline Pulping
A New Headspace Gas Chromatographic Method for the Determination of Methanol Content in Paper Materi
A novel method for the determination of black liquor viscosity by multiple headspace extraction gas
Rapid determination of residual formaldehyde in formaldehyde related polymer latexes by headspace ga
A Practical Headspace Gas Chromatographic Method for the Determination of Oxalate in Bleaching Efflu
A Novel Headspace Gas Chromatographic Method for in Situ Monitoring of Monomer Conversion during Pol
Determination of Methanol in Pulp Washing Filtrates by Desiccated Full Evaporation Headspace Gas Chr
Rapid Determination of Hydrogen Peroxide in Pulp Bleaching Effluents by Headspace Gas Chromatography
Rapid Determination of Formaldehyde in Sanitary Paper Napkins for Product Quality Control by Headspa
Homogeneous Grafting Poly(Methyl Methacrylate) on Cellulose by Atom Transfer Radical Polymerization
顶空气相色谱法快速检测卫生纸中的细菌含量
麦草浆氧脱木素过程中甲醇生成的经验模型
ClO2氧化处理对马尾松CTMP浆羧基含量及物理强度的影响
清远某电子垃圾拆解区河流底泥中重金属和多氯联苯的复合污染
珠江水质和含氮消毒副产物的时空变化
2种藻菌固定化改进方法的比较及优化研究
焦化废水尾水中被O_3/UV氧化的组分辨析及关键组分动力学
电驱动下的环境污染物厌氧生物转化-电子转移原理和应用实例
流化床与沸腾床内部微生物群落演变与分析
原位盐脱水顶空气相色谱测煤焦化废水的苯酚含量
焦化废水处理过程中溴代二口恶英类化合物的去除途径和生成机理
2种形态铜绿假单胞菌在氯消毒过程中消毒副产物研究
疏水改性MCM-41材料对邻苯二甲酸二丁酯的吸附
不同煅烧温度制备的Mn、N掺杂TiO2光催化性能研究
焦化废水处理工程运行能耗的单元解析模型——以OHO流化床工艺为例
基于流体分离污泥的异质性：微生物活性和群落结构
硝化污泥保藏特性的研究
Mg（OH）2引入方式对过氧化氢漂白废液中主要成分的影响
Mg（OH）2引入方式对过氧化氢漂白废液中主要成分的影响
ClO_2氧化处理对马尾松CTMP浆羧基含量及物理强度的影响
ClO_2氧化处理对马尾松CTMP浆羧基含量及物理强度的影响
液比对尾叶桉硫酸盐法制浆过程中脱木素的影响
速生桉木硫酸盐法蒸煮中液比对甲醇生成的影响
速生桉木硫酸盐法蒸煮中液比对甲醇生成的影响
还原性预处理对麦草浆中铁离子去除效果初探
还原性预处理对麦草浆中铁离子去除效果初探
O3／UV深度处理焦化废水的条件控制及其效能评估
珠江水体中有机物分布、组成及与消毒副产物生成的关系
酸化蛭石的表面有机修饰及其对疏水性微污染物的吸附
龙塘镇电子垃圾拆解区土壤和河流底泥重金属赋存形态及生态风险
焦化废水生物出水溶解性有机物特性光谱表征
硼氢化钠预处理在纸浆过氧化氢漂白过程中的作用机制
硼氢化钠预处理对桉木浆漂白过程中过氧化氢无效分解及纸浆性能的影响
桉木硫酸盐法制浆及氧脱木素优化工艺的能耗评价
期刊信息
  • 《中国环境监测》
  • 中国科技核心期刊
  • 主管单位:国家环境保护部
  • 主办单位:中国环境监测总站
  • 主编：王业耀
  • 地址：北京市朝阳区安外大羊坊8号大院乙
  • 邮编：100012
  • 邮箱：iaob@chinajournal.net.cn
  • 电话：010-84943033
  • 国际标准刊号：ISSN：1002-6002
  • 国内统一刊号：ISSN：11-2861/X
  • 邮发代号:
  • 获奖情况:
  • 国家环境保护总局首届期刊评比一等奖
  • 国内外数据库收录:
  • 美国化学文摘（网络版）,中国中国科技核心期刊,中国北大核心期刊（2004版）,中国北大核心期刊（2008版）,中国北大核心期刊（2011版）,中国北大核心期刊（2014版）,中国北大核心期刊（2000版）
  • 被引量:16554