基于平衡常数k和CO2密度ρ1曲线关系,提出了一个关联溶质在超临界CO2中溶解度改进模型。与常用的Chrastil、Adachi-Lu、del Valle-Aguilera、Sparks模型关联18种溶质在超临界CO2中溶解度对比表明:该模型精度最高,其绝对平均偏差的平均值(AAD)为5.81%,而Chrastil、Adachi-Lu、del Valle-Aguilera和Sparks模型的AAD分别为10.66%、7.38%、9.91%和7.00%。从而为溶质在超临界CO2中的溶解度计算提供新的思路。
Based on the relationship of an association equilibrium constant k and the supercritical carbon dioxide(SC-CO2) density ρ1,a modified density-based model for correlation of the solubilities of some compounds in SC-CO2 is established.The comparison with Chrastil,Adachi-Lu,del Valle-Aguilera,and Sparks models shows that the proposed model is in the best accordance with experimental data,and that average absolute relative discrepancy is 5.81%,while the average absolute relative discrepancies for Chrastil,Adachi-Lu,del Valle-Aguilera,and Sparks model are 10.66%,7.38%,9.91% and 7.00%,respectively.So,it may provide a method for calculation of the solubilities of solutes in SC-CO2.